ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
An Allyl Uranium(IV) Sandwich Complex: Are ϕ Bonding Interactions Possible?
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed, 12 citations in OpenAlex.
- Hydrogen-Induced, Unexpectedly Strong 8c-2e ϕ Bond in AnJACS Au · 2026Article
- Computational Investigation of the Chemical Bond between An(III) Ions and Soft-Donor Ligands.Inorganic chemistry · 2025Article
- Theoretical Investigation on One-Electron ϕ···ϕ Bonding in Diuranium Inverse Sandwich UInorganic chemistry · 2024Article
- Alkyl Coordination inOrganometallics · 2024Article
- Synthesis and comparison of iso-structural f-block metal complexes (Ce, U, Np, Pu) featuringChemical science · 2023Article
- Thorium- and Uranium-Mediated C-H Activation of a Silyl-Substituted Cyclobutadienyl Ligand.Inorganic chemistry · 2022Article
- An Allyl Uranium(IV) Sandwich Complex: Are ϕ Bonding Interactions Possible?Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 1 country.
Funding
Abstract
A method to explore head-to-head ϕ back-bonding from uranium f-orbitals into allyl π* orbitals has been pursued. Anionic allyl groups were coordinated to uranium with tethered anilide ligands, then the products were investigated by using NMR spectroscopy, single-crystal XRD, and theoretical methods. The (allyl)silylanilide ligand, N-((dimethyl)prop-2-enylsilyl)-2,6-diisopropylaniline (LH), was used as either the fully protonated, singly deprotonated, or doubly deprotonated form, thereby highlighting the stability and versatility of the silylanilide motif. A free, neutral allyl group was observed in UI
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Registered trials
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