ArticleInorganic chemistry2022
The Chemistry of Zirconium/Carboxylate Clustering Process: Acidic Conditions to Promote Carboxylate-Unsaturated Octahedral Hexamers and Pentanuclear Species.
Article in Inorganic chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Atomically Precise Cluster Cocatalysts: Missing Link toward Heterogenized Photocatalytic Systems.ACS nano · 2026Review
- 6FDA-Based Co-Polyimide Membranes Incorporating Modulated MOF-808s for Olefin/Paraffin Gas Separations.Membranes · 2025Article
- Heterogeneous Photocatalytic Systems Formed by Compound [ZrChemSusChem · 2025Article
- One-Component Catalytic Electrodes from Metal-Organic Frameworks Covalently Linked to an Anion Exchange Ionomer.Molecules (Basel, Switzerland) · 2025Article
- Mechanism Insight into Direct Amidation Catalyzed by Zr Salts: Evidence of Zr Oxo Clusters as Active Species.Inorganic chemistry · 2024Article
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Authors and funding
9 authors.
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Abstract
Clustering chemistry is a key point in the design and synthesis of the secondary building units that comprise metal-organic frameworks (MOFs) based on group IV metals. In this work, the first stages of the zirconium-carboxylate clustering process in alcohol/water mixtures are studied in detail using the monocarboxylic benzoic and hydroxybenzoic acids to avoid the polymerization. Mass spectroscopy measurements performed on the reactions revealed the presence of hexa- and pentanuclear species even at low pH values and also evidenced the acid-base nature and pH dependence of the transformation between both species. The control on the chemistry governing the equilibria between these species has allowed us to isolate six new compounds in the solid state. The single-crystal X-ray diffraction analysis revealed that they are closely related to the well-known [Zr
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