ArticleACS sustainable chemistry & engineering2021
Design of Glycerol-Based Solvents for the Immobilization of Palladium Nanocatalysts: A Hydrogenation Study.
Article in ACS sustainable chemistry & engineering, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 31 citations in OpenAlex.
- Enabling Base-Free Direct C-H Arylation of Thiophene Derivatives: Glycerol-Derived Solvents as Active Reaction Media.ChemSusChem · 2026Article
- Photochemical synthesis of Pd nanocatalysts stabilized by biomass-derived polymers: from colloidal to supported systems in batch and flow.RSC advances · 2025Article
- Eco-Friendly Solvents for Bioactives: Solubilization of Hydroxycinnamic Acids in Glycerol-Derived Ethers.ACS sustainable chemistry & engineering · 2025Article
- A Ligand-Free Approach towards Coumarin Analogs via Natural Deep Eutectic Solvent-Mediated Suzuki-Miyaura Coupling.Molecules (Basel, Switzerland) · 2024Article
- Novel Catalyst Composites of Ni- and Co-Based Nanoparticles Supported on Inorganic Oxides for Fatty Acid Hydrogenations.Nanomaterials (Basel, Switzerland) · 2023Article
- Deep Eutectic Solvents as à-la-Carte Medium for Transition-Metal-Catalyzed Organic Processes.Molecules (Basel, Switzerland) · 2022Review
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Authors and funding
5 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Twenty-one green solvents, including glycerol-derived ethers, and their eutectic mixtures with two renewable ammonium salts, were used for the straightforward synthesis, stabilization, and immobilization of palladium nanoparticles (Pd NPs). The nature of the solvent allows tuning of the characteristics and properties of resulting catalytic systems in terms of particle size and morphology, stability, reactivity, and recoverability. Pd NPs immobilized in glycerol-based solvents were applied in the catalytic hydrogenation of alkenes, alkynes, and carbonyl compounds, as well as in the selective semihydrogenation of alkynes to alkenes. The optimal experimental parameters and the influence on the reactivity of the physicochemical properties of solvent, mainly the viscosity, were studied. Moreover, the most active and recoverable catalytic system,
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Registered trials
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