ArticleChemistry of materials : a publication of the American Chemical Society2022
Direct and Linker-Exchange Alcohol-Assisted Hydrothermal Synthesis of Imide-Linked Covalent Organic Frameworks.
Article in Chemistry of materials : a publication of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Unlocking carrier confluence in covalent organic frameworks for efficient photoreduction of dilute nitrate to ammonia.Nature communications · 2026Article
- Covalent/metal-organic framework membranes with tailored pore functionality for accurate ion separation.Chemical science · 2025Review
- Fabrication of flexibility-rigidity alternately assembled solid-state luminescence covalent organic frameworks: application to rifampicin antibiotics detection and latent fingerprint recognition.Mikrochimica acta · 2025Article
- Probing Defects in Covalent Organic Frameworks.ACS applied materials & interfaces · 2024Review
- Review
- Article
- Reducing undesired solubility of squarephaneic tetraimide for use as an organic battery electrode material.Faraday discussions · 2024Article
- Green synthesis of bifunctional phthalocyanine-porphyrin cofs in water for efficient electrocatalytic CONational science review · 2023Article
- Aromatic Amine-Functionalized Covalent Organic Frameworks (COFs) for COACS applied materials & interfaces · 2023Article
- Squarephaneic Tetraanhydride: A Conjugated Square-Shaped Cyclophane for the Synthesis of Porous Organic Materials.Angewandte Chemie (International ed. in English) · 2022Article
- Squarephaneic Tetraanhydride: A Conjugated Square-Shaped Cyclophane for the Synthesis of Porous Organic Materials.Angewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2022Article
- Synthesis of Covalent Organic Frameworks (COFs)-Nanocellulose Composite and Its Thermal Degradation Studied by TGA/FTIR.Polymers · 2022Article
- Electrochemical (Bio)Sensors Based on Covalent Organic Frameworks (COFs).Sensors (Basel, Switzerland) · 2022Review
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Covalent organic frameworks (COFs) are an extensively studied class of porous materials, which distinguish themselves from other porous polymers in their crystallinity and high degree of modularity, enabling a wide range of applications. However, the established synthetic protocols for the synthesis of stable and crystalline COFs, such as imide-linked COFs, often requires the use of high boiling solvents and toxic catalysts, making their synthesis expensive and environmentally harmful. Herein, we report a new environmentally friendly strategy-an alcohol-assisted hydrothermal polymerization approach (aaHTP) for the synthesis of a wide range of crystalline and porous imide-linked COFs. This method allows us to gain access to new COFs and to avoid toxic solvents by up to 90% through substituting commonly used organic solvent mixtures with water and small amounts of n-alcohols without being restricted to water-soluble linker molecules. Additionally, we use the aaHTP to demonstrate an eco-friendly COF-to-COF transformation of an imine-linked COF into a novel imide-linked COF via linkage replacement, inaccessible using published reaction conditions.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.