ArticleJournal of the American Chemical Society2022
Oxygen-Atom Defect Formation in Polyoxovanadate Clusters via Proton-Coupled Electron Transfer.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Evidence for Site-Specific Tunneling in H Atom Uptake at the Surface of Polyoxovanadate-Alkoxides.JACS Au · 2026Article
- Redox-State-Driven Site Selectivity and Kinetic Gating in Polyoxovanadate Methylation.Inorganic chemistry · 2026Article
- The Effect of Nanoparticle Structure on the Thermodynamics and Kinetics of Proton-Coupled Electron Transfer Reactions to V2O5.Journal of the American Chemical Society · 2026Article
- Revisiting the Robin-Day Classification through Switchable Electronic States in Multimetallic Vanadium Oxides.Journal of the American Chemical Society · 2026Article
- Review
- Impact of Anionic Dopants on H Atom Uptake at Polyoxovanadate-Alkoxide Surfaces.Inorganic chemistry · 2025Article
- Electrochemically Determined and Structurally Justified Thermochemistry of H atom Transfer on Ti-Oxo Nodes of the Colloidal Metal-Organic Framework Ti-MIL-125.Journal of the American Chemical Society · 2024Article
- Vanadium Substitution Dictates H Atom Uptake at Lindqvist-type Polyoxotungstates.Inorganic chemistry · 2024Article
- Impact of Surface Ligand Identity and Density on the Thermodynamics of H Atom Uptake at Polyoxovanadate-Alkoxide Surfaces.Inorganic chemistry · 2024Article
- Selective Hydrogenation of Azobenzene to Hydrazobenzene via Proton-Coupled Electron Transfer from a Polyoxotungstate Cluster.JACS Au · 2024Article
- Heterometal Dopant Changes the Mechanism of Proton-Coupled Electron Transfer at the Polyoxovanadate-Alkoxide Surface.Journal of the American Chemical Society · 2024Article
- Efficient Hole Transfer from CdSe Quantum Dots Enabled by Oxygen-Deficient Polyoxovanadate-Alkoxide Clusters.Nano letters · 2023Article
- Vertex Differentiation Strategy for Tuning the Physical Properties ofInorganic chemistry · 2023Article
- Coupled reaction equilibria enable the light-driven formation of metal-functionalized molecular vanadium oxides.Nature communications · 2023Article
- Proton-Coupled Electron Transfer at the Surface of Polyoxovanadate-Alkoxide Clusters.Accounts of chemical research · 2023Article
- Regioselectivity of concerted proton-electron transfer at the surface of a polyoxovanadate cluster.Chemical science · 2023Article
- Connecting Thermodynamics and Kinetics of Proton Coupled Electron Transfer at Polyoxovanadate Surfaces Using the Marcus Cross Relation.Inorganic chemistry · 2023Article
- Coordination-induced bond weakening of water at the surface of an oxygen-deficient polyoxovanadate cluster.Chemical science · 2022Article
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The uptake of hydrogen atoms (H-atoms) into reducible metal oxides has implications in catalysis and energy storage. However, outside of computational modeling, it is difficult to obtain insight into the physicochemical factors that govern H-atom uptake at the atomic level. Here, we describe oxygen-atom vacancy formation in a series of hexavanadate assemblies via proton-coupled electron transfer, presenting a novel pathway for the formation of defect sites at the surface of redox-active metal oxides. Kinetic investigations reveal that H-atom transfer to the metal oxide surface occurs through concerted proton-electron transfer, resulting in the formation of a transient V
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