Evidence map›Paper›PMID 35274165›Full record

ReviewTopics in current chemistry (Cham)2022

Enantioselective Allylic C-H Bond Oxidation of Olefins Using Copper Complexes of Chiral Oxazoline Based Ligands.

Saadi Samadi, Hamid Arvinnezhad, Saber Nazari, Shiva Majidian

Abstract readReview
PubMed Publisher
In one paragraph

Review in Topics in current chemistry (Cham), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Saadi SamadiLaboratory of Asymmetric Synthesis, Department of Chemistry, Faculty of Science, University of Kurdistan, 66177-15175, Sanandaj, Iran. s.samadi@uok.ac.ir.
Hamid ArvinnezhadLaboratory of Asymmetric Synthesis, Department of Chemistry, Faculty of Science, University of Kurdistan, 66177-15175, Sanandaj, Iran.
Saber NazariLaboratory of Asymmetric Synthesis, Department of Chemistry, Faculty of Science, University of Kurdistan, 66177-15175, Sanandaj, Iran.
Shiva MajidianLaboratory of Asymmetric Synthesis, Department of Chemistry, Faculty of Science, University of Kurdistan, 66177-15175, Sanandaj, Iran.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This review article discusses historical and contemporary research studies of asymmetric allylic oxidation of olefins using homogeneous and heterogeneous copper complexes of various kinds of oxazoline-based ligands, until the end of 2021. It is revealed that this strategy is a powerful method to form a new stereogenic center bearing an oxygen substituent adjacent to an unchanged C=C bond. Enantioselectivities as well as chemical yields, and also the reactivity, are strongly dependent on the type of substrate, oxidant, the copper salt and its oxidation state, ligand structure, temperature, nature of the solvent, and additives such as phenylhydrazine and porous materials.

Indexed as

AlkenesCopperCatalysisLigandsStereoisomerismAlkenesCopperLigandsAllylic esterAsymmetric allylic C–H bond oxidationCopper complexes of chiral oxazoline ligandsOlefinPerester

Identifiers

PMID35274165

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.