ReviewMolecules (Basel, Switzerland)2022
The Phosphorus Bond, or the Phosphorus-Centered Pnictogen Bond: The Covalently Bound Phosphorus Atom in Molecular Entities and Crystals as a Pnictogen Bond Donor.
Review in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Short Sb···Sb Contacts in Polymorphic Tris(p-Tolyl)Antimony: A Hallmark of Organoantimony(III) Solid-State Chemistry?Angewandte Chemie (International ed. in English) · 2026Article
- Negative σ-Holes on Fluorine in Molecules Revisited: Halogen Bonding or Counterintuitive, Anti-Electrostatic Interactions?International journal of molecular sciences · 2026Article
- Electronic and Optical Properties of Graphene Oxide Quantum Dots: DFT Insights of Mixed Vacancy and Dopants.ACS omega · 2026Article
- Article
- Molecular Electrostatic Surface Potential: A Predictive Framework for Noncovalent Interactions and Adsorption Characteristics in Molecular Entities.International journal of molecular sciences · 2026Review
- Halogen Bond via an Electrophilic π-Hole on Halogen in Molecules: Does It Exist?International journal of molecular sciences · 2024Article
- Search for Osme Bonds with π Systems as Electron Donors.Molecules (Basel, Switzerland) · 2023Article
- Methylammonium Tetrel Halide Perovskite Ion Pairs and Their Dimers: The Interplay between the Hydrogen-, Pnictogen- and Tetrel-Bonding Interactions.International journal of molecular sciences · 2023Article
- The Tetrel Bond and Tetrel Halide Perovskite Semiconductors.International journal of molecular sciences · 2023Article
- Tetrel Bonding in Anion Recognition: A First Principles Investigation.Molecules (Basel, Switzerland) · 2022Article
- Involvement of Arsenic Atom of AsFMolecules (Basel, Switzerland) · 2022Article
- The Pnictogen Bond, Together with Other Non-Covalent Interactions, in the Rational Design of One-, Two- and Three-Dimensional Organic-Inorganic Hybrid Metal Halide Perovskite Semiconducting Materials, and Beyond.International journal of molecular sciences · 2022Review
- The Pnictogen Bond: The Covalently Bound Arsenic Atom in Molecular Entities in Crystals as a Pnictogen Bond Donor.Molecules (Basel, Switzerland) · 2022Review
- The Stibium Bond or the Antimony-Centered Pnictogen Bond: The Covalently Bound Antimony Atom in Molecular Entities in Crystal Lattices as a Pnictogen Bond Donor.International journal of molecular sciences · 2022Review
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4 authors.
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Abstract
The phosphorus bond in chemical systems, which is an inter- or intramolecular noncovalent interaction, occurs when there is evidence of a net attractive interaction between an electrophilic region associated with a covalently or coordinately bonded phosphorus atom in a molecular entity and a nucleophile in another, or the same, molecular entity. It is the second member of the family of pnictogen bonds, formed by the second member of the pnictogen family of the periodic table. In this overview, we provide the reader with a snapshot of the nature, and possible occurrences, of phosphorus-centered pnictogen bonding in illustrative chemical crystal systems drawn from the ICSD (Inorganic Crystal Structure Database) and CSD (Cambridge Structural Database) databases, some of which date back to the latter part of the last century. The illustrative systems discussed are expected to assist as a guide to researchers in rationalizing phosphorus-centered pnictogen bonding in the rational design of molecular complexes, crystals, and materials and their subsequent characterization.
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