ArticleResearch (Washington, D.C.)2022
Multilayer 3D Chiral Folding Polymers and Their Asymmetric Catalytic Assembly.
Article in Research (Washington, D.C.), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Design, synthesis, and analysis of multi-layered 3D fluorescent polymers derived from anthracene and naphthalene structural units.RSC advances · 2026Article
- Synergistic 3D π-π networks enforce persistent foldamer configuration with tunable full-color circularly polarized luminescence.Communications chemistry · 2025Article
- AIE-active fluorescent probes as 'turn-off' sensors for the selective detection of CrRSC advances · 2025Article
- The Synthesis and Property Study of NH-Ac-Anchored Multilayer 3D Polymers.Molecules (Basel, Switzerland) · 2025Article
- Exploring chiral and achiral properties of novel multilayer 3D polymers: synthesis and characterization.RSC advances · 2025Article
- Enantiopure Turbo Chirality Targets in Tri-Propeller Blades: Design, Asymmetric Synthesis, and Computational Analysis.Molecules (Basel, Switzerland) · 2025Article
- C(sp)-C(sp) Lever-Based Targets of Orientational Chirality: Design and Asymmetric Synthesis.Molecules (Basel, Switzerland) · 2024Article
- Recent Advances in π-Stacking Interaction-Controlled Asymmetric Synthesis.Molecules (Basel, Switzerland) · 2024Review
- Enantioselective synthesis of [1,1'-binaphthalene]-8,8'-diyl bis(diphenylphosphane) and its derivatives.RSC advances · 2024Article
- Amino Turbo Chirality and Its Asymmetric Control.Research (Washington, D.C.) · 2024Article
- Discovery of Staircase Chirality through the Design of Unnatural Amino Acid Derivatives.Research (Washington, D.C.) · 2024Article
- Four-layer folding framework: design, GAP synthesis, and aggregation-induced emission.Frontiers in chemistry · 2023Article
- Aggregation-Induced Polarization (Frontiers in chemistry · 2022Article
- Orientational Chirality, Its Asymmetric Control, and Computational Study.Research (Washington, D.C.) · 2022Article
- A new chiral phenomenon of orientational chirality, its synthetic control and computational study.Frontiers in chemistry · 2022Article
Corrections and comments
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Authors and funding
16 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A novel class of polymers and oligomers of chiral folding chirality has been designed and synthesized, showing structurally compacted triple-column/multiple-layer frameworks. Both uniformed and differentiated aromatic chromophoric units were successfully constructed between naphthyl piers of this framework. Screening monomers, catalysts, and catalytic systems led to the success of asymmetric catalytic Suzuki-Miyaura polycouplings. Enantio- and diastereochemistry were unambiguously determined by X-ray structural analysis and concurrently by comparison with a similar asymmetric induction by the same catalyst in the asymmetric synthesis of a chiral three-layered product. The resulting chiral polymers exhibit intense fluorescence activity in a solid form and solution under specific wavelength irradiation.
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Registered trials
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