ArticleNano letters2022
Subnanometer Topological Tuning of the Liquid Intrusion/Extrusion Characteristics of Hydrophobic Micropores.
Article in Nano letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed.
- Topology-Controlled Dipolar Ordering and Wetting Thermodynamics of Water in Hydrophobic Nanotubes.The journal of physical chemistry letters · 2026Article
- Article
- Energetic and Structural Insights into Water Confined in Hydrophobic Nanopores.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Effects of Size and Porosity on the Hydrophobicity of Hierarchical Nanoparticles.Nano letters · 2025Article
- Energetic Characteristics of Hydrophobic Porous Materials as Candidates for Manufacturing of Nanorockets.The journal of physical chemistry letters · 2024Article
- Spontaneous Dipole Reorientation in Confined Water and Its Effect on Wetting/Dewetting of Hydrophobic Nanopores.ACS applied materials & interfaces · 2024Article
- Mechanism of Water Intrusion into Flexible ZIF-8: Liquid Is Not Vapor.Nano letters · 2023Article
- Effect of the Topology on Wetting and Drying of Hydrophobic Porous Materials.ACS applied materials & interfaces · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Intrusion (wetting)/extrusion (drying) of liquids in/from lyophobic nanoporous systems is key in many fields, including chromatography, nanofluidics, biology, and energy materials. Here we demonstrate that secondary topological features decorating main channels of porous systems dramatically affect the intrusion/extrusion cycle. These secondary features, allowing an unexpected bridging with liquid in the surrounding domains, stabilize the water stream intruding a micropore. This reduces the intrusion/extrusion barrier and the corresponding pressures without altering other properties of the system. Tuning the intrusion/extrusion pressures via subnanometric topological features represents a yet unexplored strategy for designing hydrophobic micropores. Though energy is not the only field of application, here we show that the proposed tuning approach may bring 20-75 MPa of intrusion/extrusion pressure increase, expanding the applicability of hydrophobic microporous materials.
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