ReviewChemical reviews2022
s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds.
Review in Chemical reviews, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.
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Who cites it
34 citing papers in PubMed, 168 citations in OpenAlex.
- Well-defined alkali metal catalysts for selective reduction of functionalized esters and carbonyl compoundsRSC advances · 2026Article
- Redox-Divergent Reactivity of a Gallium(I) Ambiphile toward an Allene, a Diyne, and Ph3PCN2.Inorganic chemistry · 2026Article
- Copper Nanoclusters with Exposed Active Sites for Highly Efficient Protoboration of C-C Multiple Bonds.Molecules (Basel, Switzerland) · 2026Article
- Potassium-Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation.Angewandte Chemie (International ed. in English) · 2026Article
- Regioselective Hydroboration of Terminal Alkenes with the Addition of Triflic Acid to Borane.The Journal of organic chemistry · 2026Article
- Insertion of COOrganometallics · 2026Article
- Ga-Based Liquid Metal Catalyst for Mechano-Assisted Carbon-Carbon Coupling Reaction.Research (Washington, D.C.) · 2026Article
- Catalytic ester hydroboration promoted by actinide complexes featuring six-membered N-heterocyclic imine ligands and actinide-alkoxides activation.Communications chemistry · 2025Article
- Regioselective Multiboration and Hydroboration of Alkenes and Alkynes Enabled by a Platinum Single-Atom Catalyst.ACS catalysis · 2025Article
- Regio- and chemoselective catalytic partial transfer hydrogenation of quinolines by dinuclear aluminum species.Nature communications · 2025Article
- Rethinking carbanion chemistry from donor substituents to weakly coordinating carbanions.Nature reviews. Chemistry · 2025Review
- Photocatalytic Hydrophosphination Using Calcium Precatalysts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Bismuth Meets Olefins: Ethylene Activation and Reversible Alkene Insertion into Bi─N Bonds.Angewandte Chemie (International ed. in English) · 2025Article
- Mechanistic Study on Copper- and Silver-Catalyzed Hydroboration of Internal Alkynes: A DFT Study.ACS organic & inorganic Au · 2025Article
- Engineering charge density in s-block potassium single-atom nanozyme for amplified ferroptosis in glioblastoma therapy.Materials today. Bio · 2025Article
- Expedient access to bora-butenolide bioisosteres by counteranion-mediated trans-hydroboration of alkynes.Nature communications · 2025Article
- Catalytic hydrogenation of acetone to isopropyl alcohol with CAlFrontiers in chemistry · 2025Article
- Catalytic hydrogenation of alkyne with planar tetracoordinate carbon in CAlFrontiers in chemistry · 2025Article
- Transition-Metal-Free Thioboration of Terminal Alkynes.JACS Au · 2024Article
- Zintl Clusters as a Platform for Lewis Acid Catalysis.Inorganic chemistry · 2024Article
Corrections and comments
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Authors and funding
3 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The addition of a B-H bond to an unsaturated bond (polarized or unpolarized) is a powerful and atom-economic tool for the synthesis of organoboranes. In recent years, s-block organometallics have appeared as alternative catalysts to transition-metal complexes, which traditionally catalyze the hydroboration of unsaturated bonds. Because of the recent and rapid development in the field of hydroboration of unsaturated bonds catalyzed by alkali (Li, Na, K) and alkaline earth (Mg, Ca, Sr, Ba) metals, we provide a detailed and updated comprehensive review that covers the synthesis, reactivity, and application of s-block metal catalysts in the hydroboration of polarized as well as unsaturated carbon-carbon bonds. Moreover, we describe the main reaction mechanisms, providing valuable insight into the reactivity of the s-block metal catalysts. Finally, we compare these s-block metal complexes with other redox-neutral catalytic systems based on p-block metals including aluminum complexes and f-block metal complexes of lanthanides and early actinides. In this review, we aim to provide a comprehensive, authoritative, and critical assessment of the state of the art within this highly interesting research area.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.