ArticleResearch (Washington, D.C.)2022
Click Modification for Polysaccharides via Novel Tunnel Transmission Phenomenon in Ionic Liquids.
Article in Research (Washington, D.C.), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed.
- Green Solvent Systems for Cellulose Dissolution and Regeneration: Hydrogen-Bond Engineering Toward Sustainable Functional Materials.ChemSusChem · 2026Review
- A Green Approach Towards Desalination: Sustainable Poly(lactic acid) Membranes for Pervaporation Desalination.Membranes · 2026Review
- Achieving Photo-Activated Circularly Polarized Room Temperature Phosphorescence from Natural Biopolymers.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Responsive circularly polarized ultralong room temperature phosphorescence materials with easy-to-scale and chiral-sensing performance.Nature communications · 2024Article
- Facile Separation of Acetic Acid from 1-Ethyl-3-methylimidazolium Acetate Ionic Liquid with the Aid of a Protic Solvent.The journal of physical chemistry. B · 2024Article
- Cellulose-Based Ultralong Room-Temperature Phosphorescence Nanomaterials with Tunable Color and High Quantum Yield via Nano-Surface Confining Effect.Research (Washington, D.C.) · 2023Article
- A Scalable Bacterial Cellulose Ionogel for Multisensory Electronic Skin.Research (Washington, D.C.) · 2022Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
It is extremely difficult to achieve a rapid and efficient modification of natural polysaccharides, due to the intrinsic strong hydrogen bonding networks and the slow mass transfer process during the reaction process. Herein, we found a fascinating anion-tunnel transmission phenomenon in the imidazolium-based ionic liquids with carboxylate anions. A novel click esterification of natural polysaccharides thus was demonstrated under a catalyst-free condition within a very short reaction time of 15 min at 0-80°C. Such a super-rapid and highly efficient modification strategy is available for various polysaccharides (cellulose, starch, inulin, pullulan, dextran, and xylan), different esterification reactions (acetification, propionation, benzoylation, and cyclohexyl formylation), and high concentrations, claiming a revolutionary potential in polysaccharide chemistry industries.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.