ArticleACS omega2022
Enhanced Photocatalytic Activity of Porphyrin Nanodisks Prepared by Exfoliation of Metalloporphyrin-Based Covalent Organic Frameworks.
Article in ACS omega, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
4 citing papers in PubMed, 21 citations in OpenAlex.
- Double Type Detection of Triiodide and Iodide Ions Using a Manganese(III) Porphyrin as Sensitive Compound.Sensors (Basel, Switzerland) · 2024Article
- Porphyrin-Based Covalent Organic Frameworks: Design, Synthesis, Photoelectric Conversion Mechanism, and Applications.Biomimetics (Basel, Switzerland) · 2023Review
- Photocatalytic Water Splitting Promoted by 2D and 3D Porphyrin Covalent Organic Polymers Synthesized by Suzuki-Miyaura Carbon-Carbon Coupling.Nanomaterials (Basel, Switzerland) · 2022Article
- Porphyrin covalent organic nanodisks synthesized using acid-assisted exfoliation for improved bactericidal efficacy.Nanoscale advances · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Organic polymers derived from covalent organic frameworks (COFs) have various applications, including photocatalysis. The synthesis of organic polymer materials from COFs to obtain higher activity for photocatalysis by changing the unit molecule has been investigated. The choice of the unit molecule is important to characterize the photochemical properties. Among various such unit molecules, porphyrins have attracted much attention as organic chromophores commonly used in photocatalytic reactions with COFs. Although COFs with various organic chromophores have been synthesized and attempts have been made to improve their photocatalytic activity, enhancing the photocatalytic activity by adjusting the layer thickness through exfoliation of COFs has yet to be fully studied. In the present study, the exfoliation of metalloporphyrin-based COFs with pyridine as the axial ligand and adjustment of the layer thickness were found to enhance the photocatalytic activity. Hydrogen generation and 3,3',5,5'-tetramethylbenzidine oxidation reactions were investigated as representative photocatalytic reactions, with the photocatalytic activity up to 7 times that of the original free-base porphyrin COFs. These results indicate that the different thicknesses synthesized by exfoliating COFs increased the photocatalytic effect of polymers.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.