Evidence map›Paper›PMID 35235698›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Calix[4]pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers.

Florian Schön, Lukas M Sigmund, Friederike Schneider, Deborah Hartmann, Matthew A Wiebe, Ian Manners, Lutz Greb

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Calix[4]pyrrolato-germane-(thf)Journal of the American Chemical Society · 2023
    Article
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Florian SchönDepartment of Chemistry, University of Victoria, Victoria, BC, V8P 5C2, Canada.
Lukas M SigmundAnorganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.ORCID http://orcid.org/0000-0003-2667-2342
Friederike SchneiderAnorganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Deborah HartmannDepartment of Chemistry, University of Victoria, Victoria, BC, V8P 5C2, Canada.ORCID http://orcid.org/0000-0001-7503-8968
Matthew A WiebeDepartment of Chemistry, University of Victoria, Victoria, BC, V8P 5C2, Canada.
Ian MannersDepartment of Chemistry, University of Victoria, Victoria, BC, V8P 5C2, Canada.ORCID http://orcid.org/0000-0002-3794-967X
Lutz GrebAnorganische Chemie, Freie Universität Berlin, Fabeckstraße 34-36, 14195, Berlin, Germany.ORCID http://orcid.org/0000-0002-5253-419X

Funding

Alexander von Humboldt-StiftungCanadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of CanadaEuropean Research Council 948708Friedrich-Ebert-StiftungStudienstiftung des Deutschen Volkes
6 · The paper itself

Abstract

High molar weight polyphosphinoboranes represent materials with auspicious properties, but their preparation requires transition metal-based catalysts. Here, calix[4]pyrrolato aluminate is shown to induce the dehydropolymerization of phosphine boranes to high molar mass polyphosphinoboranes (up to M

Indexed as

AluminumDehydropolymerizationMetal-Ligand CooperativityPolymersPolyphosphinoboranes

Identifiers

PMID35235698
PMCPMC9313825

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.