Evidence map›Paper›PMID 35226781›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Diradicals Photogeneration from Chloroaryl-Substituted Carboxylic Acids.

Lorenzo Di Terlizzi, Stefano Protti, Davide Ravelli, Maurizio Fagnoni

Open access · hybridAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
0.3field-weighted citation impact, top 51% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 4 citations in OpenAlex.

  1. Article
  2. Diradicals Photogeneration from Chloroaryl-Substituted Carboxylic Acids.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Lorenzo Di TerlizziPhotoGreen Lab, Department of Chemistry, V. Le Taramelli 10, 27100, Pavia, Italy.
Stefano ProttiPhotoGreen Lab, Department of Chemistry, V. Le Taramelli 10, 27100, Pavia, Italy.ORCID http://orcid.org/0000-0002-5313-5692
Davide RavelliPhotoGreen Lab, Department of Chemistry, V. Le Taramelli 10, 27100, Pavia, Italy.ORCID http://orcid.org/0000-0003-2201-4828
Maurizio FagnoniPhotoGreen Lab, Department of Chemistry, V. Le Taramelli 10, 27100, Pavia, Italy.ORCID http://orcid.org/0000-0003-0247-7585
University of Pavia · IT

Funding

Università degli Studi di Pavia
6 · The paper itself

Abstract

With the aim of generating new, thermally inaccessible diradicals, potentially able to induce a double-strand DNA cleavage, the photochemistry of a set of chloroaryl-substituted carboxylic acids in polar media was investigated. The photoheterolytic cleavage of the Ar-Cl bond occurred in each case to form the corresponding triplet phenyl cations. Under basic conditions, the photorelease of the chloride anion was accompanied by an intramolecular electron-transfer from the carboxylate group to the aromatic radical cationic site to give a diradical species. This latter intermediate could then undergo CO

Indexed as

Carboxylic AcidsWaterCationsDNAPhotochemistryCarboxylic AcidsCationsDNAWaterdiradicalsheterolytic cleavageintramolecular electron transferphenyl cationsphotochemistry

Identifiers

PMID35226781
PMCPMC9313617
OpenAlexW4214550094

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.