ReviewPolymers2022
Boronic Acid Esters and Anhydrates as Dynamic Cross-Links in Vitrimers.
Review in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
21 citing papers in PubMed.
- Nanoparticle-Enabled Interfacial Kinetic Control of Bond-Exchange Reactions: Insights from Biomedical Poly(ε-caprolactone)-Based Dynamic Polymers.ACS macro letters · 2026Article
- From Furfural to Reprocessable Thermosets: Diels-Alder Monomers for Dynamic Polyurethane Networks.ChemSusChem · 2026Review
- Thermosets Based on Covalent Bond Exchange: Mechanisms, Properties, and Reprocessing.Polymers · 2026Review
- Article
- Self-healing hydrogels: mechanisms and applications in biomedical and environmental fields.Biodegradation · 2026Review
- Boron-based fire retardancy for natural polymeric materials.Frontiers in chemistry · 2026Review
- Synthesis of Boronic Acid-Cross-Linked Diene-Based Polymers via Free-Radical Copolymerization.Chemistry, an Asian journal · 2026Article
- Effects of Isohexide Stereochemistry on Vinylogous Urethane Covalent Adaptable Networks.Macromolecules · 2025Article
- A review of epoxy vitrimer-based thermally conductive composites.RSC advances · 2025Review
- Nanofibrous supramolecular peptide hydrogels for controlled release of small-molecule drugs and biologics.Nature nanotechnology · 2025Article
- Current State-of-the-Art and Perspectives in the Design and Application of Vitrimeric Systems.Molecules (Basel, Switzerland) · 2025Review
- Injectable and 3D-Printable Semi-Interpenetrating Polymer Networks Based on Modified Sodium Alginate for Cell Spheroid Formation.Biomacromolecules · 2025Article
- Covalent Adaptable Networks with Tailorable Material Properties Based on Divanillin Polyimines.Biomacromolecules · 2024Article
- Tuning the Mechanical and Dynamic Properties of Elastic Vitrimers by Tailoring the Substituents of Boronic Ester.ACS materials Au · 2024Article
- Water-stable boroxine structure with dynamic covalent bonds.Nature communications · 2024Article
- Review
- On a Biobased Epoxy Vitrimer from a Cardanol Derivative Prepared by a Simple Thiol-Epoxy "Click" Reaction.ACS omega · 2024Article
- Highly Stretchable, Self-Healing, Injectable and pH Responsive Hydrogel from Multiple Hydrogen Bonding and Boron-Carbohydrate Interactions.Gels (Basel, Switzerland) · 2023Article
- Ring Opening Copolymerization of Boron-Containing Anhydride with Epoxides as a Controlled Platform to Functional Polyesters.Journal of the American Chemical Society · 2023Article
- Covalent adaptable networks using boronate linkages by incorporating TetraAzaADamantanes.Frontiers in chemistry · 2023Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Growing environmental awareness imposes on polymer scientists the development of novel materials that show a longer lifetime and that can be easily recycled. These challenges were largely met by vitrimers, a new class of polymers that merges properties of thermoplastics and thermosets. This is achieved by the incorporation of dynamic covalent bonds into the polymer structure, which provides high stability at the service temperature, but enables the processing at elevated temperatures. Numerous types of dynamic covalent bonds have been utilized for the synthesis of vitrimers. Amongst them, boronic acid-based linkages, namely boronic acid esters and boroxines, are distinguished by their quick exchange kinetics and the possibility of easy application in various polymer systems, from commercial thermoplastics to low molecular weight thermosetting resins. This review covers the development of dynamic cross-links. This review is aimed at providing the state of the art in the utilization of boronic species for the synthesis of covalent adaptable networks. We mainly focus on the synthetic aspects of boronic linkages-based vitrimers construction. Finally, the challenges and future perspectives are provided.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.