Evidence map›Paper›PMID 35211276›Full record

ArticleChemical science2022

A generalized kinetic model for compartmentalization of organometallic catalysis.

Brandon J Jolly, Nathalie H Co, Ashton R Davis, Paula L Diaconescu, Chong Liu

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Brandon J JollyDepartment of Chemistry and Biochemistry, University of California Los Angeles California 90095 USA pld@chem.ucla.edu chongliu@chem.ucla.edu.ORCID https://orcid.org/0000-0003-4991-5212
Nathalie H CoDepartment of Chemistry and Biochemistry, University of California Los Angeles California 90095 USA pld@chem.ucla.edu chongliu@chem.ucla.edu.ORCID https://orcid.org/0000-0002-7678-8653
Ashton R DavisDepartment of Chemistry and Biochemistry, University of California Los Angeles California 90095 USA pld@chem.ucla.edu chongliu@chem.ucla.edu.ORCID https://orcid.org/0000-0003-0764-0126
Paula L DiaconescuDepartment of Chemistry and Biochemistry, University of California Los Angeles California 90095 USA pld@chem.ucla.edu chongliu@chem.ucla.edu.ORCID https://orcid.org/0000-0003-2732-4155
Chong LiuDepartment of Chemistry and Biochemistry, University of California Los Angeles California 90095 USA pld@chem.ucla.edu chongliu@chem.ucla.edu.ORCID https://orcid.org/0000-0001-5546-3852

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Compartmentalization is an attractive approach to enhance catalytic activity by retaining reactive intermediates and mitigating deactivating pathways. Such a concept has been well explored in biochemical and more recently, organometallic catalysis to ensure high reaction turnovers with minimal side reactions. However, the scarcity of theoretical frameworks towards confined organometallic chemistry impedes broader utility for the implementation of compartmentalization. Herein, we report a general kinetic model and offer design guidance for a compartmentalized organometallic catalytic cycle. In comparison to a non-compartmentalized catalysis, compartmentalization is quantitatively shown to prevent the unwanted intermediate deactivation, boost the corresponding reaction efficiency (

Identifiers

PMID35211276
PMCPMC8790775

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.