ArticleGels (Basel, Switzerland)2022
Characterization of Calcium Silicate Hydrate Gels with Different Calcium to Silica Ratios and Polymer Modifications.
Article in Gels (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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11 citing papers in PubMed, 83 citations in OpenAlex.
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- Concrete Incorporating a Spent COMaterials (Basel, Switzerland) · 2026Article
- Hydration properties of belite cement prepared by lime-hydrothermal treatment of Saudi basaltic volcanic ash and glass.Scientific reports · 2025Article
- Enhancing cement properties for oil wells using MgO-PAM nanocomposites.Scientific reports · 2025Article
- Microstructural and Elemental Characterization of Calcium Silicate-Based Sealers.Nanomaterials (Basel, Switzerland) · 2025Article
- Advanced structural and compositional profiling of mineral trioxide aggregate incorporated with nano-carbonated hydroxyapatite: a comprehensive X-ray diffraction and energy dispersive X-ray investigation.Biomaterial investigations in dentistry · 2025Article
- Evaluation of the usability of trachydacitic aggregate in rigid pavements in terms of strength and durability.Scientific reports · 2024Article
- The Investigation of Compacting Cement Systems for Studying the Fundamental Process of Cement Gel Formation.Gels (Basel, Switzerland) · 2022Article
- A Study on the Cement Gel Formation Process during the Creation of Nanomodified High-Performance Concrete Based on Nanosilica.Gels (Basel, Switzerland) · 2022Article
- Investigating the Effect of Selenium Nanoparticles on Mineral Trioxide Aggregates as a Promising Novel Dental Material.Journal of International Society of Preventive & Community DentistryArticle
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Authors and funding
2 authors at 1 institution in 1 country.
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Abstract
Calcium silicate hydrate (CSH) gels, the main binding phases of hydrated cement, are the most widely utilized synthetic materials. To understand the influences of composition and polymers on the reaction kinetics and phase formation, CSH gels with varying Ca/Si ratios and amounts of poly (acrylamide-co-acrylic acid) partial sodium salt (PAAm-co-PAA) were synthesized via a direct method. The CSH gels were characterized through isothermal calorimetry, thermogravimetric analysis (TGA), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and Raman spectroscopy at different ages. By increasing the Ca/Si ratio from 0.8 to 1.0, the formation of CSH was enhanced with a 5.4% lower activation energy, whereas the incorporation of PAAm-co-PAA increased the temperature sensitivity of the reactions with an 83.3% higher activation energy. In the presence of PAAm-co-PAA, the reaction rate was retarded at an early age and the negative impact faded over time. The results of an XRD analysis indicated the formation of tobermorite as the main phase of the CSH gels, while the addition of PAAm-co-PAA resulted in a postponed calcium hydroxide consumption and CSH formation, which was confirmed by the decreased FTIR intensity of the C=O bond, Si-O stretching and Si-O bonds. The increased Raman vibrations of Si-O-Si bending Q
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