Evidence map›Paper›PMID 35188315›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Metal-Organic Frameworks as Unique Platforms to Gain Insight of σ-Hole Interactions for the Removal of Organic Dyes from Aquatic Ecosystems.

Cristina Negro, Paula Escamilla, Rosaria Bruno, Jesus Ferrando-Soria, Donatella Armentano, Emilio Pardo

Open access · greenAbstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
0.8field-weighted citation impact, top 35% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 10 citations in OpenAlex.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 2 institutions in 2 countries.

Cristina NegroInstituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980, València, Spain.ORCID http://orcid.org/0000-0002-2294-3208
Paula EscamillaInstituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980, València, Spain.ORCID http://orcid.org/0000-0002-6419-8891
Rosaria BrunoDipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, 87030, Rende, Cosenza, Italy.ORCID http://orcid.org/0000-0001-6524-3212
Jesus Ferrando-SoriaInstituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980, València, Spain.ORCID http://orcid.org/0000-0003-0987-2764
Donatella ArmentanoDipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, 87030, Rende, Cosenza, Italy.ORCID http://orcid.org/0000-0002-8502-8074
Emilio PardoInstituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna, 46980, València, Spain.ORCID http://orcid.org/0000-0002-1394-2553
Parc Científic de la Universitat de València · ESUniversity of Calabria · IT

Funding

Conselleria d'Educació, Investigació, Cultura i Esport PROMETEO/2021/054H2020 European Research Council 814804ministerio de ciencia e innovación PID2019-104778GB-I00ministerio de Ciencia e Innovación CEX2019-000919-M
6 · The paper itself

Abstract

The combination of high crystallinity and rich host-guest chemistry in metal-organic frameworks (MOFs), have situated them in an advantageous position, with respect to traditional porous materials, to gain insight on specific weak noncovalent supramolecular interactions. In particular, sulfur σ-hole interactions are known to play a key role in the biological activity of living beings as well as on relevant molecular recognitions processes. However, so far, they have been barely explored. Here, we describe both how the combination of the intrinsic features of MOFs, especially the possibility of using single-crystal X-ray crystallography (SCXRD), can be an extremely valuable tool to gain insight on sulfur σ-hole interactions, and how their rational exploitation can be enormously useful in the efficient removal of harmful organic molecules from aquatic ecosystems. Thus, we have used a MOF, prepared from the amino acid L-methionine and possessing channels decorated with -CH

Indexed as

Metal-Organic FrameworksAdsorptionColoring AgentsEcosystemSulfurWaterColoring AgentsMetal-Organic FrameworksSulfurWaterhost-guest chemistrymetal-organic frameworksorganic dyeswater remediationσ-Hole Interaction

Identifiers

PMID35188315
PMCPMC9314587
OpenAlexW4213381534

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.