ArticleACS omega2022
Principal Component Analysis of Surface-Enhanced Raman Scattering Spectra Revealing Isomer-Dependent Electron Transport in Spiropyran Molecular Junctions: Implications for Nanoscale Molecular Electronics.
Article in ACS omega, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
8 citing papers in PubMed.
- Photogated two conductive pathways of donor-acceptor Stenhouse adducts in single-molecule junctions.Nature communications · 2026Article
- SERS-guided photodynamic therapy: pioneering strategies in advanced cancer diagnosis and treatment.Discover nano · 2025Review
- Interpretable Multiscale Convolutional Neural Network for Classification and Feature Visualization of Weak Raman Spectra of Biomolecules at Cell Membranes.ACS sensors · 2025Article
- Methods for the analysis, interpretation, and prediction of single-molecule junction conductance behaviour.Chemical science · 2024Review
- An Orthogonal Conductance Pathway in Spiropyrans for Well-Defined Electrosteric Switching Single-Molecule Junctions.Small (Weinheim an der Bergstrasse, Germany) · 2024Article
- Surface-Enhanced Raman Spectroscopy-Based Detection of Micro-RNA Biomarkers for Biomedical Diagnosis Using a Comparative Study of Interpretable Machine Learning Algorithms.Applied spectroscopy · 2024Article
- Intermolecular and Electrode-Molecule Bonding in a Single Dimer Junction of Naphthalenethiol as Revealed by Surface-Enhanced Raman Scattering Combined with Transport Measurements.Journal of the American Chemical Society · 2023Article
- Label-free detection and discrimination of respiratory pathogens based on electrochemical synthesis of biomaterials-mediated plasmonic composites and machine learning analysis.Biosensors & bioelectronics · 2023Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The characterization of single-molecule structures could provide significant insights into the operation mechanisms of functional devices. Structural transformation via isomerization has been extensively employed to implement device functionalities. Although single-molecule identification has recently been achieved using near-field spectroscopy, discrimination between isomeric forms remains challenging. Further, the structure-function relationship at the single-molecule scale remains unclear. Herein, we report the observation of the isomerization of spiropyran in a single-molecule junction (SMJ) using simultaneous surface-enhanced Raman scattering (SERS) and conductance measurements. SERS spectra were used to discriminate between isomers based on characteristic peaks. Moreover, conductance measurements, in conjunction with the principal component analysis of the SERS spectra, clearly showed the isomeric effect on the conductance of the SMJ.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.