ArticleACS catalysis2021
Identifying the Imperative Role of Metal-Olefin Interactions in Catalytic C-O Reductive Elimination from Nickel(II).
Article in ACS catalysis, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed, 11 citations in OpenAlex.
- Mechanism of Ni-Catalyzed Photochemical Halogen Atom-Mediated C(spJournal of the American Chemical Society · 2024Article
- Synthesis of Nickel(I)-Bromide Complexes via Oxidation and Ligand Displacement: Evaluation of Ligand Effects on Speciation and Reactivity.Journal of the American Chemical Society · 2023Article
- A C-to-O atom-swapping reaction sequence enabled by Ni-catalyzed decarbonylation of lactones.Chemical science · 2022Article
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4 authors at 1 institution in 1 country.
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Abstract
We present a series of experimental and computational mechanistic investigations of an unusually facile example of Ni-catalyzed C-O bond formation. Our method, originally reported in 2016, involves the formation of cyclic enol ethers from vinyl iodides bearing pendant alcohol groups. Our findings suggest that the observed reactivity arises from the coordination of the olefin in the vinyl iodide starting material and the enol ether product with Ni(0) intermediates. Density functional theory calculations reveal a plausible catalytic mechanism involving a Ni(II)/Ni(0) redox cycle featuring two-electron C-I oxidative addition and C-O reductive elimination steps. The direct formation of a
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