Evidence map›Paper›PMID 35178850›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Activating a [FeFe] Hydrogenase Mimic for Hydrogen Evolution under Visible Light.

Philipp Buday, Chizuru Kasahara, Elisabeth Hofmeister, Daniel Kowalczyk, Micheal K Farh, Saskia Riediger, Martin Schulz, Maria Wächtler, Shunsuke Furukawa, Masaichi Saito and 6 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Activating a [FeFe] Hydrogenase Mimic for Hydrogen Evolution under Visible Light.Angewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

16 authors.

Philipp BudayInstitute of Inorganic and Analytical Chemistry, Friedrich Schiller University Jena, Humboldtstraße 8, 07743, Jena, Germany.ORCID 0000-0002-2410-2728
Chizuru KasaharaInstitute of Inorganic and Analytical Chemistry, Friedrich Schiller University Jena, Humboldtstraße 8, 07743, Jena, Germany.
Elisabeth HofmeisterDepartment Functional Interfaces, Leibniz Institute of Photonic Technology Jena (Leibniz-IPHT), Albert-Einstein-Straße 9, 07745, Jena, Germany.
Daniel KowalczykInstitute of Chemical Engineering, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Micheal K FarhInstitute of Inorganic and Analytical Chemistry, Friedrich Schiller University Jena, Humboldtstraße 8, 07743, Jena, Germany.ORCID 0000-0003-3669-9127
Saskia RiedigerInstitute of Organic Chemistry II and Advanced Materials, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Martin SchulzDepartment Functional Interfaces, Leibniz Institute of Photonic Technology Jena (Leibniz-IPHT), Albert-Einstein-Straße 9, 07745, Jena, Germany.ORCID 0000-0003-4989-5207
Maria WächtlerDepartment Functional Interfaces, Leibniz Institute of Photonic Technology Jena (Leibniz-IPHT), Albert-Einstein-Straße 9, 07745, Jena, Germany.ORCID 0000-0001-6073-1970
Shunsuke FurukawaDepartment of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama City, Saitama, 338-8570, Japan.
Masaichi SaitoDepartment of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama City, Saitama, 338-8570, Japan.ORCID 0000-0001-6176-3034
Dirk ZiegenbalgInstitute of Chemical Engineering, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID 0000-0001-6104-4953
Stefanie GräfeInstitute of Physical Chemistry, Friedrich Schiller University Jena, Helmholtzweg 4, 07743, Jena, Germany.ORCID 0000-0002-6428-7528
Peter BäuerleInstitute of Organic Chemistry II and Advanced Materials, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID 0000-0003-2017-4414
Stephan KupferInstitute of Physical Chemistry, Friedrich Schiller University Jena, Helmholtzweg 4, 07743, Jena, Germany.ORCID 0000-0002-1747-5809
Benjamin Dietzek-IvanšićDepartment Functional Interfaces, Leibniz Institute of Photonic Technology Jena (Leibniz-IPHT), Albert-Einstein-Straße 9, 07745, Jena, Germany.ORCID 0000-0002-2842-3537
Wolfgang WeigandInstitute of Inorganic and Analytical Chemistry, Friedrich Schiller University Jena, Humboldtstraße 8, 07743, Jena, Germany.ORCID 0000-0001-5177-1006

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Inspired by the active center of the natural [FeFe] hydrogenases, we designed a compact and precious metal-free photosensitizer-catalyst dyad (PS-CAT) for photocatalytic hydrogen evolution under visible light irradiation. PS-CAT represents a prototype dyad comprising π-conjugated oligothiophenes as light absorbers. PS-CAT and its interaction with the sacrificial donor 1,3-dimethyl-2-phenylbenzimidazoline were studied by steady-state and time-resolved spectroscopy coupled with electrochemical techniques and visible light-driven photocatalytic investigations. Operando EPR spectroscopy revealed the formation of an active [Fe

Indexed as

HydrogenaseIron-Sulfur ProteinsCatalysisHydrogenLightHydrogenHydrogenaseIron-Sulfur Proteins[FeFe] Hydrogenase MimicsH2 ProductionOligothiopheneOperando EPR SpectroscopyPhotocatalysis

Identifiers

PMID35178850
PMCPMC9313588

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.