ArticleChemical science2022
Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Structural and spectroscopic characterization of a Tb(IV) polyoxometalate.Nature communications · 2026Article
- Pressure-Induced Stabilization of Terbium(IV) in CsTb(CrOJournal of the American Chemical Society · 2026Article
- Exploratory Synthetic Studies of the Praseodymium/Di-2-Pyridyl Ketoxime System Leads to Unusual Reactivity and Interesting New Molecules.Inorganic chemistry · 2026Article
- A Guide to Nonaqueous Electrochemistry of f-Element Complexes.Inorganic chemistry · 2026Article
- Ligand Design Criteria for the Stability of High Oxidation State Praseodymium Complexes.Inorganic chemistry · 2026Article
- Isolation of Ce(iv) centered polyoxoalkoxide sandwich-type complexes allows comparison of metal-oxygen bond covalency.Chemical science · 2025Article
- Supramolecular assemblies of tetravalent terbium complex units: syntheses, structure, and materials properties.Chemical science · 2025Article
- High Pressure Synthesis of PrAngewandte Chemie (International ed. in English) · 2025Article
- Redox and Photochemical Reactivity of Cerium(IV) Carbonate and Carboxylate Complexes Supported by a Tripodal Oxygen Ligand.Inorganic chemistry · 2025Article
- Divalent Intermediates in Lanthanide-Based Photocatalysts: Spectroscopic Characterization and Reactivity.Inorganic chemistry · 2025Article
- Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state.Chemical science · 2024Article
- Tetravalent Cerium Alkyl and Benzyl Complexes.Journal of the American Chemical Society · 2024Article
- Tetravalent Terbium Chelates: Stability Enhancement and Property Tuning.Precision chemistry · 2023Article
- Structural distortion by alkali metal cations modulates the redox and electronic properties of CeChemical science · 2023Article
- Back to the future of organolanthanide chemistry.Chemical science · 2023Review
- Photoluminescence processes inRoyal Society open science · 2022Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Among the 14 lanthanide elements (Ce-Lu), until recently, the tetravalent oxidation state was readily accessible in solution only for cerium while Pr(iv), Nd(iv), Dy(iv) and Tb(iv) had only been detected in the solid state. The triphenylsiloxide ligand recently allowed the isolation of molecular complexes of Tb(iv) and Pr(iv) providing an unique opportunity of investigating the luminescent properties of Ln(iv) ions. Here we have expanded the coordination studies of the triphenylsiloxide ligand with Ln(iii) and Ln(iv) ions and we report the first observed luminescence emission spectra of Pr(iv) complexes which are assigned to a ligand-based emission on the basis of the measured lifetime and computational studies. Binding of the ligand to the Pr(iv) ion leads to an unprecedented large shift of the ligand triplet state which is relevant for future applications in materials science.
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Registered trials
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