ArticleAngewandte Chemie (International ed. in English)2022
Ultra-Tough Elastomers from Stereochemistry-Directed Hydrogen Bonding in Isosorbide-Based Polymers.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Lignin-dynamic networks break the strength-toughness trade-off in thermoplastic elastomers.Nature communications · 2026Article
- One-pot organocatalysis of diacrylates to functional polyesters for toughening polylactide.National science review · 2025Article
- Effects of Isohexide Stereochemistry on Vinylogous Urethane Covalent Adaptable Networks.Macromolecules · 2025Article
- Damage-resistant and body-temperature shape memory skin-mimic elastomer for biomedical applications.Science advances · 2025Article
- Biodegradable Polyurethane Derived from Hydroxylated Polylactide with Superior Mechanical Properties.Polymers · 2024Article
- Chemically Recyclable and Biodegradable Vulcanized Rubber.ACS sustainable chemistry & engineering · 2024Article
- Xylose- and Nucleoside-Based Polymers via Thiol-ene Polymerization toward Sugar-Derived Solid Polymer Electrolytes.ACS applied polymer materials · 2024Article
- Injectable, thermo-sensitive and self-adhesive supramolecular hydrogels built from binary herbal small molecules towards reusable antibacterial coatings.RSC advances · 2024Article
- Structural Metamorphoses of d-Xylose Oxetane- and Carbonyl Sulfide-Based PolymersJournal of the American Chemical Society · 2023Article
- Click Step-Growth Polymerization andAccounts of chemical research · 2022Article
- Ultra-Tough Elastomers from Stereochemistry-Directed Hydrogen Bonding in Isosorbide-Based Polymers.Angewandte Chemie (International ed. in English) · 2022Article
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The remarkable elasticity and tensile strength found in natural elastomers are challenging to mimic. Synthetic elastomers typically feature covalently cross-linked networks (rubbers), but this hinders their reprocessability. Physical cross-linking via hydrogen bonding or ordered crystallite domains can afford reprocessable elastomers, but often at the cost of performance. Herein, we report the synthesis of ultra-tough, reprocessable elastomers based on linear alternating polymers. The incorporation of a rigid isohexide adjacent to urethane moieties affords elastomers with exceptional strain hardening, strain rate dependent behavior, and high optical clarity. Distinct differences were observed between isomannide and isosorbide-based elastomers where the latter displays superior tensile strength and strain recovery. These phenomena are attributed to the regiochemical irregularities in the polymers arising from their distinct stereochemistry and respective inter-chain hydrogen bonding.
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