Evidence map›Paper›PMID 35164194›Full record

ArticleMolecules (Basel, Switzerland)2022

Effect of Fatty Acid Polyunsaturation on Synthesis and Properties of Emulsion Polymers Based on Plant Oil-Based Acrylic Monomers.

Vasylyna Kirianchuk, Zoriana Demchuk, Yehor Polunin, Ananiy Kohut, Stanislav Voronov, Andriy Voronov

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.2field-weighted citation impact, top 65% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 2 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 3 institutions in 2 countries.

Vasylyna KirianchukDepartment of Organic Chemistry, Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013 Lviv, Ukraine.ORCID 0000-0003-0927-262X
Zoriana DemchukDepartment of Coatings and Polymeric Materials, North Dakota State University, Fargo, ND 58102, USA.ORCID 0000-0003-2629-2235
Yehor PoluninDepartment of Coatings and Polymeric Materials, North Dakota State University, Fargo, ND 58102, USA.
Ananiy KohutDepartment of Organic Chemistry, Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013 Lviv, Ukraine.
Stanislav VoronovDepartment of Organic Chemistry, Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013 Lviv, Ukraine.
Andriy VoronovDepartment of Coatings and Polymeric Materials, North Dakota State University, Fargo, ND 58102, USA.
Lviv Polytechnic National University · UANorth Dakota State University · USOak Ridge National Laboratory · US

Funding

North Dakota Corn Utilization Council not available 00North Dakota Department of Agriculture not available 00North Dakota Soybean Council not available 00
6 · The paper itself

Abstract

This study demonstrated that polymerization behavior of plant oil-based acrylic monomers (POBMs) synthesized in one-step transesterification reaction from naturally rich in oleic acid olive, canola, and high-oleic soybean oils is associated with a varying mass fraction of polyunsaturated fatty acid fragments (linoleic (C18:2) and linolenic (C18:3) acid esters) in plant oil. Using miniemulsion polymerization, a range of stable copolymer latexes was synthesized from 60 wt.% of each POBM and styrene to determine the impact of POBM chemical composition (polyunsaturation) on thermal and mechanical properties of the resulted polymeric materials. The unique composition of each plant oil serves as an experimental tool to determine the effect of polyunsaturated fatty acid fragments on POBM polymerization behavior and thermomechanical properties of crosslinked films made from POBM-based latexes. The obtained results show that increasing polyunsaturation in the copolymers results in an enhanced crosslink density of the latex polymer network which essentially impacts the mechanical properties of the films (both Young's modulus and toughness). Maximum toughness was observed for crosslinked latex films made from 50 wt.% of each POBM in the monomer feed.

Indexed as

AcrylatesEmulsionsFatty AcidsPlant OilsPolymersAcrylatesEmulsionsFatty AcidsPlant OilsPolymersbiobased latexescrosslinked latex filmsemulsion polymerizationplant oil-based acrylic monomersplant oils

Identifiers

PMID35164194
PMCPMC8839316
OpenAlexW4210334747

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.