Mineral Montmorillonite Valorization by Developing Ni and Mo-Ni Catalysts for Third-Generation Green Diesel Production.

Sotiris Lycourghiotis, Eleana Kordouli, John Zafeiropoulos, Christos Kordulis, Kyriakos Bourikas

Abstract read

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Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

5 authors.

Sotiris LycourghiotisSchool of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, GR-26335 Patras, Greece.

Eleana KordouliDepartment of Chemistry, University of Patras, GR-26504 Patras, Greece.ORCID 0000-0002-6931-3035

John ZafeiropoulosSchool of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, GR-26335 Patras, Greece.

Christos KordulisDepartment of Chemistry, University of Patras, GR-26504 Patras, Greece.ORCID 0000-0002-4259-8624

Kyriakos BourikasSchool of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, GR-26335 Patras, Greece.ORCID 0000-0003-4793-1163

Funding

Special Account for Research Funds of the Hellenic Open University 80246

6 · The paper itself

Abstract

Four Ni catalysts and one Mo-Ni catalyst supported on montmorillonite were synthesized, characterized by various techniques and evaluated, under solvent-free conditions, for the production of green diesel from waste cooking oil. The optimum Ni content was found to be 20 wt.%. The addition of 2 wt.% Mo to the catalyst resulted in a considerable increase in the amount of green diesel hydrocarbons. The Mo species, moreover, led to a decrease in the (C15 + C17)/(C16 + C18) ratio, which is beneficial from the viewpoint of carbon atom economy. The promoting action of Mo was mainly attributed to the synergy between the oxygen vacancies on the surface of the well-dispersed Mo(V) and Mo(VI) oxides and the neighboring Ni

Indexed as

green (renewable) dieselmontmorillonitenickel catalystsselective deoxygenationwaste cooking oil

Identifiers

PMID35163908

DOI10.3390/molecules27030643

PMCPMC8838441

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