ArticleACS omega2022
Investigation of the Coordination Chemistry of a Bisamidinate Ferrocene Ligand with Cu, Ag, and Au.
Article in ACS omega, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
7 authors.
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Abstract
The coordination chemistry of a ferrocene ligand with one bulky amidinate function attached to each ring toward two different coinage metal precursors was investigated. In dependence of the metal and the co-ligands, "ansa" type structures and non-bridged structures were obtained. Six different compounds are reported. In the "ansa" type structures, short Fe-M (M = Cu, Ag) distances were observed in the molecular structures in the solid state. However, theoretical calculations (DFT) did not reveal a stabilizing metal-metal interaction. Instead, dispersion interactions within the ligand and between the ligand and metal seem to represent the main stabilization forces.
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