ArticleScience advances2022
The chemical evolution of solid electrolyte interface in sodium metal batteries.
Article in Science advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
What it found
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Who cites it
18 citing papers in PubMed, 147 citations in OpenAlex.
- Anode-Free Sodium Metal Batteries: From Materials Design to System-Level Integration.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Design Guidelines for Anode Modifications to Eliminate Soft Short Circuits in Anode-Free Na Batteries Under High Current Density With Large-Capacity Plating, Demonstrated via Initiated Chemical Vapor Deposition (iCVD).Angewandte Chemie (International ed. in English) · 2026Article
- Dual-domain solvent-locked electrolyte enabled durable 4.5 V-class sodium batteries.Nature communications · 2026Article
- Manipulating cation solvation equilibrium in sole-solvent electrolyte for fast-charging and wide-temperature-range sodium metal batteries.Nature communications · 2026Article
- Self-Regulating Sodium-Ion Battery Materials: From Phase Reconstruction to Functional Activation.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Interfacial failure mechanisms and design principles in solid-state sodium batteries.Chemical science · 2026Review
- Improving Electrolyte Sustainability for Sodium-Ion Capacitors by Combining a Bio-Based Solvent With a Low-Fluorine Salt.ChemSusChem · 2026Article
- Weak-solvation dilution for interphase preservation and extreme low-temperature sodium-ion storage.National science review · 2026Article
- Unveiling the Electrolyte and Solid Electrolyte Interphase in Sodium Ion Batteries: Mechanisms, Progress, and Perspectives.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Single atom activated multi-stage active sites for thoroughgoing sodium utilization.Nature communications · 2025Article
- Recent Trends in Artificial SEI Layers for Controlling Dendrite Formation and Enhancing Cycle Life: Toward Stable and Durable Sodium Metal Batteries.Small (Weinheim an der Bergstrasse, Germany) · 2025Review
- 3D Printed Sodiophilic Reduced Graphene Oxide/Diamane Microlattice Aerogel for Enhanced Sodium Metal Battery Anodes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Salt-in-presalt electrolyte solutions for high-potential non-aqueous sodium metal batteries.Nature nanotechnology · 2025Article
- Composition and Structure of the solid electrolyte interphase on Na-Ion Anodes Revealed by Exo- and Endogenous Dynamic Nuclear Polarization─NMR Spectroscopy.Journal of the American Chemical Society · 2024Article
- Synergistic interface and structural engineering for high initial coulombic efficiency and stable sodium storage in metal sulfides.Chemical science · 2024Article
- Progress inMagnetic resonance letters · 2024Review
- Research progress of organic liquid electrolyte for sodium ion battery.Frontiers in chemistry · 2023Review
- Exploring ionic liquid-laden metal-organic framework composite materials as hybrid electrolytes in metal (ion) batteries.Frontiers in chemistry · 2022Review
Corrections and comments
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Authors and funding
4 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The solid electrolyte interface (SEI) formed on the anode is one of the key factors that determine the life span of sodium metal batteries (SMBs). However, the continuous evolution of SEI during charging/discharging processes complicates the fundamental understanding of its chemistry and structure. In this work, we studied the underlying mechanisms of the protection effect offered by the SEI derived from sodium difluoro(oxalato)borate (NaDFOB). In situ nuclear magnetic resonance (NMR) shows that the prior reduction of DFOB anion contributes to the SEI formation, and it suppresses the decomposition of carbonate solvents. Depth-profiling x-ray photoelectron spectroscopy and high-resolution solid-state NMR reveal that the DFOB anion is gradually turned into borate and fluoride-rich SEI with cycling. The protection effect of SEI reaches the optimum at 50 cycles, which triples the life span of SMB. The detailed investigations provide valuable guidelines for the SEI engineering.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.