ArticleNature chemistry2022
A terminal neptunium(V)-mono(oxo) complex.
Article in Nature chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
21 citing papers in PubMed, 0 citations in OpenAlex.
- Resolving the innerChemical science · 2026Article
- Transient Triamidoamine Neptunium(V)-Mono(Imido) Complexes: C-H Activations and Hydrogen Atom Transfer Driven by Effective Nuclear Charge.Journal of the American Chemical Society · 2026Article
- Plutonium(III) versus uranium(III) and samarium(III) in small molecule activation chemistry.Nature communications · 2026Article
- Electronic Structure, Ligand Effects, and Chemical Reactivity of the Ground and Low-Lying Excited Electronic States of NpOMolecules (Basel, Switzerland) · 2026Article
- A Guide to Nonaqueous Electrochemistry of f-Element Complexes.Inorganic chemistry · 2026Article
- Transuranium organometallic chemistry.Nature reviews. Chemistry · 2025Review
- Redoxable Deep Eutectic Solvent Boosts Recovery Efficiency of Neptunium.Chem & bio engineering · 2025Article
- Product Variation in Reactions of MIInorganic chemistry · 2025Article
- Computational Investigation of the Chemical Bond between An(III) Ions and Soft-Donor Ligands.Inorganic chemistry · 2025Article
- UInorganic chemistry · 2025Article
- A tetrahedral neptunium(V) complex.Nature chemistry · 2024Article
- Proton-Coupled Electron Transfer at the PuJournal of the American Chemical Society · 2024Article
- Progress in Nonaqueous Molecular Uranium Chemistry: Where to Next?Inorganic chemistry · 2024Article
- Arene-, Chlorido-, and Imido-Uranium Bis- and Tris(boryloxide) Complexes.Inorganic chemistry · 2024Article
- N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal-Carbene Bond Length Shortening Versus Lanthanide Congeners.Journal of the American Chemical Society · 2024Article
- Carbene Complexes of Plutonium: Structure, Bonding, and Divergent Reactivity to Lanthanide Analogs.Journal of the American Chemical Society · 2024Article
- Actinide inverse trans influence versus cooperative pushing from below and multi-center bonding.Nature communications · 2023Article
- Synthesis and comparison of iso-structural f-block metal complexes (Ce, U, Np, Pu) featuringChemical science · 2023Article
- Progress in the chemistry of molecular actinide-nitride compounds.Chemical science · 2023Review
- Synthesis and Characterization of Yttrium Methanediide Silanide Complexes.Inorganic chemistry · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
11 authors at 4 institutions in 4 countries.
Funding
Abstract
Neptunium was the first actinide element to be artificially synthesized, yet, compared with its more famous neighbours uranium and plutonium, is less conspicuously studied. Most neptunium chemistry involves the neptunyl di(oxo)-motif, and transuranic compounds with one metal-ligand multiple bond are rare, being found only in extended-structure oxide, fluoride or oxyhalide materials. These combinations stabilize the required high oxidation states, which are otherwise challenging to realize for transuranic ions. Here we report the synthesis, isolation and characterization of a stable molecular neptunium(V)-mono(oxo) triamidoamine complex. We describe a strong Np≡O triple bond with dominant 5f-orbital contributions and σ
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.