Evidence map›Paper›PMID 35137732›Full record

ArticleDalton transactions (Cambridge, England : 2003)2022

Ligand design of zero-field splitting in trigonal prismatic Ni(II) cage complexes.

Anthony J Campanella, Tyler M Ozvat, Joseph M Zadrozny

Abstract read
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In one paragraph

Article in Dalton transactions (Cambridge, England : 2003), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Quantum Mimicry With Inorganic Chemistry.Comments on modern chemistry. Part A, Comments on inorganic chemistry : a journal of critical discussion of the current literature · 2024
    Article
  2. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Anthony J CampanellaDepartment of Chemistry, Colorado State University, Fort Collins, CO 80523, USA. joe.zadrozny@colostate.edu.ORCID http://orcid.org/0000-0002-2806-1118
Tyler M OzvatDepartment of Chemistry, Colorado State University, Fort Collins, CO 80523, USA. joe.zadrozny@colostate.edu.ORCID http://orcid.org/0000-0002-7558-6099
Joseph M ZadroznyDepartment of Chemistry, Colorado State University, Fort Collins, CO 80523, USA. joe.zadrozny@colostate.edu.ORCID http://orcid.org/0000-0002-1309-6545

Funding

A Coordination Chemistry Approach to High-Field EPR ImagingR21EB027293 · NIBIB · COLORADO STATE UNIVERSITY · PI ZADROZNY, JOSEPH M · 2018 to 2020
$534k
400 MHz NMR Spectrometer for CSU Central Instrument FacilityS10OD021814 · OD · COLORADO STATE UNIVERSITY · PI RITHNER, CHRISTOPHER D · 2016 to 2016
$517k
NIBIB NIH HHS R21 EB027293NIH HHS S10 OD021814
6 · The paper itself

Abstract

Complexes of encapsulated metal ions are promising potential metal-based electron paramagnetic resonance imaging (EPRI) agents due to zero-field splitting. Herein, we synthesize and magnetically characterize a series of five new Ni(II) complexes based on a clathrochelate ligand to provide a new design strategy for zero-field splitting in an encaged environment. UV-Vis and X-ray single-crystal diffraction experiments demonstrate slight physical and electronic structure changes as a function of the differing substituents. The consequence of these changes at the remote apical and sidearm positions of the encaging ligands is a zero-field splitting parameter (

Identifiers

PMID35137732
PMCPMC8992015

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.