Evidence map›Paper›PMID 35132810›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2022

Highly Crowded Twisted Thienylene-Phenylene Structures: Evidence for Through-Space Orbital Coupling in a [4]Catenated Topology.

Tanja Desirée Leitner, Jan Simon von Glasenapp, Rainer Herges, Elena Mena-Osteritz, Peter Bäuerle

Abstract read
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Tanja Desirée LeitnerInstitute of Organic Chemistry II and Advanced Materials, University of Ulm, Albert-Einstein-Allee 11, Ulm, 89081, Germany.
Jan Simon von GlasenappOtto Diels-Institute of Organic Chemistry, Christian-Albrechts University Kiel, Otto-Hahn-Platz 4, Kiel, 24098, Germany.
Rainer HergesOtto Diels-Institute of Organic Chemistry, Christian-Albrechts University Kiel, Otto-Hahn-Platz 4, Kiel, 24098, Germany.ORCID https://orcid.org/0000-0002-6396-6991
Elena Mena-OsteritzInstitute of Organic Chemistry II and Advanced Materials, University of Ulm, Albert-Einstein-Allee 11, Ulm, 89081, Germany.
Peter BäuerleInstitute of Organic Chemistry II and Advanced Materials, University of Ulm, Albert-Einstein-Allee 11, Ulm, 89081, Germany.ORCID https://orcid.org/0000-0003-2017-4414

Funding

scholarship within the framework of the Graduate Funding by the Ministry of Science, Research and the Arts of Baden-WürttembergUniversity of Ulm
6 · The paper itself

Abstract

Sterically highly crowded and twisted thienylene-phenylenes are synthesized and structurally characterized. Single-crystal X-ray structure analyses and theoretical studies give evidence of through-space delocalization of π-electrons of peripheral (hetero)aromatic rings in toroidal and catenated topology.

Indexed as

ACID calculationthienylene-phenylenesthrough-space conjugationtoroidal pz-orbital couplingX-ray structure analysis

Identifiers

PMID35132810
PMCPMC9259713

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.