ArticleAngewandte Chemie (International ed. in English)2022
Photo-Imprinting of the Helical Organization in Liquid-Crystal Networks Using Achiral Monomers and Circularly Polarized Light.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed, 23 citations in OpenAlex.
- Achieving robust cholesteric liquid crystal polymer networks with high luminescence dissymmetry factor.Nature communications · 2026Article
- Selective chiral dimerization and folding driven by arene-perfluoroarene force.Chemical science · 2024Article
- A Photomechanical Film in which Liquid Crystal Design Shifts the Absorption into the Visible Light Range.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Scale effect of circularly polarized luminescent signal of matter.National science review · 2023Article
- Circular depolarization spectroscopy: A new tool to study photo-imprinting of chirality.Chirality · 2023Article
- Charge transport in liquid crystal network of terthiophene-siloxane block molecules.Chemical communications (Cambridge, England) · 2022Article
- Photo-Imprinting of the Helical Organization in Liquid-Crystal Networks Using Achiral Monomers and Circularly Polarized Light.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 3 countries.
Funding
Abstract
Control over molecular motion is facilitated in materials with highly ordered nanoscale structures. Here we report on the fabrication of cholesteric liquid-crystal networks by circularly polarized light irradiation, without the need for chiral dopant or plasticizer. The polymer network is obtained by photopolymerization of a smectic achiral diacrylate mesogen consisting of an azobenzene core and discrete oligodimethylsiloxane tails. The synchronous helical photoalignment and photopolymerization originate from the cooperative movement of the mesogens ordered in well-defined responsive structures, together with the flexibility of the oligodimethylsiloxane blocks. The resulting thin films show excellent thermal stability and light-induced memory features with reversible responses. Additionally, we demonstrate the fabrication of photo-patterned films of liquid-crystal networks with opposite helical senses. These findings provide a new method to make light-controllable chiroptical materials with exciting applications in optics and photonics.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.