ArticleChemical science2022
The inversion of tetrahedral p-block element compounds: general trends and the relation to the second-order Jahn-Teller effect.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Si-H Activation via Dynamic Permutational Isomerism: A Ligand-Directed Route to Dehydrogenative Coupling.Angewandte Chemie (International ed. in English) · 2025Article
- Exploring Jahn-Teller distortions: a local vibrational mode perspective.Journal of molecular modeling · 2024Article
- Calix[4]pyrrolato-germane-(thf)Journal of the American Chemical Society · 2023Article
- Metallomimetic Chemistry of a Cationic, Geometrically Constrained Phosphine in the Catalytic Hydrodefluorination and Amination of Ar-F Bonds.Journal of the American Chemical Society · 2023Article
- Dihydrogen Activation with a Neutral, Intermolecular Silicon(IV)-Amine Frustrated Lewis Pair.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Calix[4]pyrrolato gallate: square planar-coordinated gallium(iii) and its metal-ligand cooperative reactivity with COChemical science · 2022Article
- Dual Reactivity of a Geometrically Constrained Phosphenium Cation.Angewandte Chemie (International ed. in English) · 2022Article
- Geometrically constrained square pyramidal phosphoranide.Chemical science · 2022Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The tetrahedron is the primary structural motif among the p-block elements and determines the architecture of our bio- and geosphere. However, a broad understanding of the configurational inversion of tetrahedral compounds is missing. Here, we report over 250 energies (DLPNO-CCSD(T)) for square planar inversion of third- and fourth-period element species of groups 13, 14, and 15. Surprisingly low inversion barriers are identified for compounds of industrial relevance (
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