ArticleiScience2022
Mechanistic insight into deep holes from interband transitions in Palladium nanoparticle photocatalysts.
Article in iScience, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Photo-electrochemical reduction of PFAS in complex water matrices.Nature communications · 2026Article
- Deciphering the Photocatalysis Mechanism of Semimetallic Bismuth Nanoparticles.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Interband and Intraband Hot Carrier-Driven Photocatalysis on Plasmonic Bimetallic Nanoparticles: A Case Study of Au-Cu Alloy Nanoparticles.ACS nanoscience Au · 2024Article
- From Precious to Earth-Abundant Metallic Nanoparticles: A Trend of Interband Transitions in Photocatalyzed Nitrobenzene Reduction.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Photocatalysis of Metallic Nanoparticles: Interband vs Intraband Induced Mechanisms.The journal of physical chemistry. C, Nanomaterials and interfaces · 2023Review
Corrections and comments
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Authors and funding
6 authors.
Funding
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Abstract
Utilizing hot electrons generated from localized surface plasmon resonance is of widespread interest in the photocatalysis of metallic nanoparticles. However, hot holes, especially generated from interband transitions, have not been fully explored for photocatalysis yet. In this study, a photocatalyzed Suzuki-Miyaura reaction using mesoporous Pd nanoparticle photocatalyst served as a model to study the role of hot holes. Quantum yields of the photocatalysts increase under shorter wavelength excitations and correlate to "deeper" energy of the holes from the Fermi level. This work suggests that deeper holes in the
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