ArticleProceedings of the National Academy of Sciences of the United States of America2022
A polarization scheme that resolves cross-peaks with transient absorption and eliminates diagonal peaks in 2D spectroscopy.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Multidimensional Infrared Spectroscopy as a Bioanalytical Technique.Chemical reviews · 2026Review
- Characterization of dynamics of encapsulated small molecule Nile red in biodegradable polymer using 2D IR methods.The Journal of chemical physics · 2026Article
- Resolving State-Specific Energy Flow in Metal Nanoclusters Using 2D Electronic Spectroscopy.The journal of physical chemistry letters · 2026Review
- Diels-Alder reaction affords circumpyrene tetracarboxydiimide with excited state intramolecular charge transfer character.Communications chemistry · 2026Article
- Disordered light-harvesting aggregates can host functional vibronic couplings at room temperature.Nature communications · 2026Article
- Advances in Probing Amyloid Heterogeneity Using Vibrational Spectroscopy and Imaging.The journal of physical chemistry. B · 2025Review
- Scattering Elimination in 2D IR Immune from Detector Artifacts.The journal of physical chemistry. B · 2024Article
- Suppressing sidechain modes and improving structural resolution for 2D IR spectroscopy via vibrational lifetimes.The Journal of chemical physics · 2024Article
- Simultaneously Measured Kinetics of Two Amyloid Polymorphs Using Cross Peak Specific 2D IR Spectroscopy.The journal of physical chemistry letters · 2023Article
- Low- and high-frequency vibrations synergistically enhance singlet exciton fission through robust vibronic resonances.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Anisotropic dynamics of an interfacial enzyme active site observed using tethered substrate analogs and ultrafast 2D IR spectroscopy.The Journal of chemical physics · 2023Article
- Phycobilisome's Exciton Transfer Efficiency Relies on an Energetic Funnel Driven by Chromophore-Linker Protein Interactions.Journal of the American Chemical Society · 2023Article
- Phase stable, shot-to-shot measurement of third- and fifth-order two-quantum correlation spectra using a pulse shaper in the pump-probe geometry.The Journal of chemical physics · 2022Article
- A polarization scheme that resolves cross-peaks with transient absorption and eliminates diagonal peaks in 2D spectroscopy.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
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3 authors.
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Abstract
Two-dimensional (2D) optical spectroscopy contains cross-peaks that are helpful features for determining molecular structure and monitoring energy transfer, but they can be difficult to resolve from the much more intense diagonal peaks. Transient absorption (TA) spectra contain transitions similar to cross-peaks in 2D spectroscopy, but in most cases they are obscured by the bleach and stimulated emission peaks. We report a polarization scheme, <0°,0°,+θ
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