ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Heterodinuclear Mg(II)M(II) (M=Cr, Mn, Fe, Co, Ni, Cu and Zn) Complexes for the Ring Opening Copolymerization of Carbon Dioxide/Epoxide and Anhydride/Epoxide.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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17 citing papers in PubMed.
- A reflection on 'Bimetallic mechanism operating in the copolymerization of propylene oxide with carbon dioxide catalyzed by cobalt-salen complexes'.Chemical science · 2025Article
- Block COACS macro letters · 2025Article
- General, Quantified Structure-Performance Correlations for Synergistic Heteronuclear Electro‑, Polymerization, and Asymmetric Catalysts.ACS catalysis · 2025Review
- Understanding the Effect of M(III) Choice in Heterodinuclear Polymerization Catalysts.Inorganic chemistry · 2024Article
- Heterogeneous Iron-Based Catalysts for Organic Transformation Reactions: A Brief Overview.Molecules (Basel, Switzerland) · 2024Review
- Choline Halide-Based Deep Eutectic Solvents as Biocompatible Catalysts for the Alternating Copolymerization of Epoxides and Cyclic Anhydrides.ACS sustainable chemistry & engineering · 2024Article
- Al(III)/K(I) Heterodinuclear Polymerization Catalysts Showing Fast Rates and High Selectivity for Polyester Polyols.ACS catalysis · 2024Article
- Evaluating Heterodinuclear Mg(II)M(II) (M = Mn, Fe, Ni, Cu, and Zn) Catalysts for the Chemical Recycling of Poly(cyclohexene carbonate).ACS catalysis · 2023Article
- Correlating Metal Redox Potentials to Co(III)K(I) Catalyst Performances in Carbon Dioxide and Propene Oxide Ring Opening Copolymerization.Angewandte Chemie (International ed. in English) · 2023Article
- Structural Metamorphoses of d-Xylose Oxetane- and Carbonyl Sulfide-Based PolymersJournal of the American Chemical Society · 2023Article
- Cationic tetranuclear macrocyclic CaCoChemical science · 2023Article
- Understanding catalytic synergy in dinuclear polymerization catalysts for sustainable polymers.Nature communications · 2023Article
- Solid-State Chemical Recycling of Polycarbonates to Epoxides and Carbon Dioxide Using a Heterodinuclear Mg(II)Co(II) Catalyst.Journal of the American Chemical Society · 2022Article
- Simple yttrium salts as highly active and controlled catalysts for the atom-efficient synthesis of high molecular weight polyesters.Chemical science · 2022Article
- Synergic Heterodinuclear Catalysts for the Ring-Opening Copolymerization (ROCOP) of Epoxides, Carbon Dioxide, and Anhydrides.Accounts of chemical research · 2022Article
- Chain end-group selectivity using an organometallic Al(iii)/K(i) ring-opening copolymerization catalyst delivers high molar mass, monodisperse polyesters.Chemical science · 2022Article
- Heterodinuclear Mg(II)M(II) (M=Cr, Mn, Fe, Co, Ni, Cu and Zn) Complexes for the Ring Opening Copolymerization of Carbon Dioxide/Epoxide and Anhydride/Epoxide.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
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Abstract
The catalysed ring opening copolymerizations (ROCOP) of carbon dioxide/epoxide or anhydride/epoxide are controlled polymerizations that access useful polycarbonates and polyesters. Here, a systematic investigation of a series of heterodinuclear Mg(II)M(II) complexes reveals which metal combinations are most effective. The complexes combine different first row transition metals (M(II)) from Cr(II) to Zn(II), with Mg(II); all complexes are coordinated by the same macrocyclic ancillary ligand and by two acetate co-ligands. The complex syntheses and characterization data, as well as the polymerization data, for both carbon dioxide/cyclohexene oxide (CHO) and endo-norbornene anhydride (NA)/cyclohexene oxide, are reported. The fastest catalyst for both polymerizations is Mg(II)Co(II) which shows propagation rate constants (k
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