Evidence map›Paper›PMID 35113718›Full record

ArticleScience (New York, N.Y.)2022

Diversification of aliphatic C-H bonds in small molecules and polyolefins through radical chain transfer.

Timothy J Fazekas, Jill W Alty, Eliza K Neidhart, Austin S Miller, Frank A Leibfarth, Erik J Alexanian

Open access · greenAbstract read
In one paragraph

Article in Science (New York, N.Y.), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 59 papers.

0numbers the graph read from it
0cells of the map it votes in
59citing papers in PubMed
23.2field-weighted citation impact, top 1% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

59 citing papers in PubMed, 224 citations in OpenAlex.

  1. Functionalization of strong C(spChemical science · 2026
    Article
  2. Article
  3. Boosting Natural Rubber Performance by Backbone Rigid Functionalization.Angewandte Chemie (International ed. in English) · 2026
    Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Direct Polymer-on-Polymer Grafting of Polyolefins under Visible Light.Journal of the American Chemical Society · 2026
    Article
  10. Article
  11. Article
  12. Hydrogen Atom Transfer Chemistry for Chemical Upcycling of Commodity Polymers.Polymer science & technology (Washington, D.C.) · 2026
    Article
  13. Article
  14. Article
  15. Article
  16. Article
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  18. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 1 institution in 1 country.

Timothy J FazekasDepartment of Chemistry, University of North Carolina-Chapel Hill, Chapel Hill, NC 27599, USA.ORCID 0000-0003-1094-3769
Jill W AltyDepartment of Chemistry, University of North Carolina-Chapel Hill, Chapel Hill, NC 27599, USA.ORCID 0000-0002-9780-1343
Eliza K NeidhartDepartment of Chemistry, University of North Carolina-Chapel Hill, Chapel Hill, NC 27599, USA.ORCID 0000-0001-7663-7268
Austin S MillerDepartment of Chemistry, University of North Carolina-Chapel Hill, Chapel Hill, NC 27599, USA.ORCID 0000-0002-0947-8006
Frank A LeibfarthDepartment of Chemistry, University of North Carolina-Chapel Hill, Chapel Hill, NC 27599, USA.ORCID 0000-0001-7737-0331
Erik J AlexanianDepartment of Chemistry, University of North Carolina-Chapel Hill, Chapel Hill, NC 27599, USA.ORCID 0000-0002-0256-2133
University of North Carolina at Chapel Hill · US

Funding

Synthesis of Bioactive Small Molecule Building BlocksR35GM118055 · NIGMS · UNIV OF NORTH CAROLINA CHAPEL HILL · PI Jeffrey S Johnson · 2016 to 2026
$5.0M
Innovative Transformations of Fundamental Synthetic Building BlocksR35GM131708 · NIGMS · UNIV OF NORTH CAROLINA CHAPEL HILL · PI Erik John Alexanian · 2019 to 2026
$3.9M
NIGMS NIH HHS R35 GM118055NIGMS NIH HHS R35 GM131708
6 · The paper itself

Abstract

The ability to selectively introduce diverse functionality onto hydrocarbons is of substantial value in the synthesis of both small molecules and polymers. Herein, we report an approach to aliphatic carbon-hydrogen bond diversification using radical chain transfer featuring an easily prepared

Indexed as

CarbonChemical PhenomenaChemistry Techniques, SyntheticHydrogenHydrogen BondingIndicators and ReagentsMolecular StructurePolyenesCarbonHydrogenIndicators and ReagentsPL 732Polyenes

Identifiers

PMID35113718
PMCPMC8889563
OpenAlexW4210632457

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.