Evidence map›Paper›PMID 35098233›Full record

ArticleJACS Au2022

Polymer End Group Control through a Decarboxylative Cobalt-Mediated Radical Polymerization: New Avenues for Synthesizing Peptide, Protein, and Nanomaterial Conjugates.

Meri Ayurini, Peter G Chandler, Paul D O'Leary, Ruoxin Wang, David Rudd, Karen D Milewska, Lara R Malins, Ashley M Buckle, Joel F Hooper

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in JACS Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.7field-weighted citation impact, top 35% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 10 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 4 institutions in 2 countries.

Meri AyuriniDepartment of Chemistry, Monash University, Clayton, 3800 Victoria, Australia.
Peter G ChandlerDepartment of Biochemistry and Molecular Biology, Biomedicine Discovery Institute, Monash University, Clayton, 3800 Victoria, Australia.
Paul D O'LearyDepartment of Chemistry, Monash University, Clayton, 3800 Victoria, Australia.
Ruoxin WangDepartment of Chemical Engineering, Monash University, Clayton, 3800 Victoria, Australia.
David RuddMonash Institute of Pharmaceutical Science, Parkville, 3052 Victoria, Australia.
Karen D MilewskaResearch School of Chemistry, Australian National University, Acton, 2601 Australian Capital Territory, Australia.
Lara R MalinsResearch School of Chemistry, Australian National University, Acton, 2601 Australian Capital Territory, Australia.ORCID https://orcid.org/0000-0002-7691-6432
Ashley M BuckleDepartment of Biochemistry and Molecular Biology, Biomedicine Discovery Institute, Monash University, Clayton, 3800 Victoria, Australia.ORCID https://orcid.org/0000-0003-2943-9044
Joel F HooperDepartment of Chemistry, Monash University, Clayton, 3800 Victoria, Australia.ORCID https://orcid.org/0000-0002-9941-2034
Monash University · AUAustralian National University · AUAustralian Regenerative Medicine Institute · AUPertamina (Indonesia) · ID

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Cobalt-mediated radical polymerizations (CMRPs) have been initiated by the radical decarboxylation of tetrachlorophthalimide activated esters. This allows for the controlled radical polymerization of activated monomers across a broad temperature range with a single cobalt species, with the incorporation of polymer end groups derived from simple carboxylic acid derivatives and termination with an organozinc reagent. This method has been applied to the synthesis of a polymer/graphene conjugate and a water-soluble protein/polymer conjugate, demonstrating the first examples of CMRP in graphene and protein conjugation.

Identifiers

PMID35098233
PMCPMC8790747
OpenAlexW3215603660

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.