Evidence map›Paper›PMID 35090125›Full record

ArticleLangmuir : the ACS journal of surfaces and colloids2022

Interfacial Charge Transfer Complexes in TiO

Claudio Imparato, Gerardino D'Errico, Wojciech Macyk, Marcin Kobielusz, Giuseppe Vitiello, Antonio Aronne

Open access · hybridAbstract read
In one paragraph

Article in Langmuir : the ACS journal of surfaces and colloids, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
0.7field-weighted citation impact, top 40% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 15 citations in OpenAlex.

  1. Article
  2. Mild Synthesis of Ag-Decorated TiOACS materials Au · 2026
    Article
  3. Article
  4. Salicylic Acid-Modified Sm-TiOThe journal of physical chemistry. C, Nanomaterials and interfaces · 2024
    Article
  5. Bimetallic TiOMolecules (Basel, Switzerland) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 2 institutions in 2 countries.

Claudio ImparatoDepartment of Chemical, Materials and Production Engineering, University of Naples Federico II, P.le V. Tecchio 80, 80125 Napoli, Italy.ORCID https://orcid.org/0000-0003-1725-7008
Gerardino D'ErricoDepartment of Chemical Sciences, University of Naples Federico II, Via Cinthia, 80126 Napoli, Italy.ORCID https://orcid.org/0000-0001-6383-8618
Wojciech MacykFaculty of Chemistry, Jagiellonian University, ul. Gronostajowa 2, Kraków 30-387, Poland.ORCID https://orcid.org/0000-0002-1317-6115
Marcin KobieluszFaculty of Chemistry, Jagiellonian University, ul. Gronostajowa 2, Kraków 30-387, Poland.ORCID https://orcid.org/0000-0003-2707-0415
Giuseppe VitielloDepartment of Chemical, Materials and Production Engineering, University of Naples Federico II, P.le V. Tecchio 80, 80125 Napoli, Italy.ORCID https://orcid.org/0000-0003-3389-6942
Antonio AronneDepartment of Chemical, Materials and Production Engineering, University of Naples Federico II, P.le V. Tecchio 80, 80125 Napoli, Italy.ORCID https://orcid.org/0000-0002-2711-6789
University of Naples Federico II · ITJagiellonian University · PL

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metal oxide-organic hybrid semiconductors exhibit specific properties depending not only on their composition but also on the synthesis procedure, and particularly on the functionalization method, determining the interaction between the two components. Surface adsorption is the most common way to prepare organic-modified metal oxides. Here a simple sol-gel route is described as an alternative, finely controlled strategy to synthesize titanium oxide-based materials containing organic molecules coordinated to the metal. The effect of the molecular structure of the ligands on the surface properties of the hybrids is studied using three enediols able to form charge transfer complexes: catechol, dopamine, and ascorbic acid. For each system, the process conditions driving the transition from the sol to chemical, physical, or particulate gels are explored. The structural, optical, and photoelectrochemical characterization of the amorphous hybrid materials shows analogies and differences related to the organic component. In particular, electron paramagnetic resonance (EPR) spectroscopy at room temperature reveals the presence of organic radical species with different evolution and stability, and photocurrent measurements prove the effective photosensitization of TiO

Identifiers

PMID35090125
PMCPMC8830207
OpenAlexW4210694210

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.