ArticleScience advances2022
Metal-free carbocatalyst for room temperature acceptorless dehydrogenation of N-heterocycles.
Article in Science advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed, 36 citations in OpenAlex.
- Cobalt Nanoparticles Confined in Defective Carbon Matrices for Robust Intermittent COAngewandte Chemie (International ed. in English) · 2026Article
- Article
- Mechanistic Insights in Acceptorless Dehydrogenation of N-Heterocycles Using Graphenes as Carbocatalysts.ACS applied materials & interfaces · 2025Article
- Selective semihydrogenation of acetylene in ethylene using defect-rich boron nitride catalyst from flux reconstruction.Nature communications · 2025Article
- Enable biomass-derived alcohols mediated alkylation and transfer hydrogenation.Nature communications · 2024Article
- Article
- Continuous Room-Temperature Hydrogen Release from Liquid Organic Carriers in a Photocatalytic Packed-Bed Flow Reactor.ChemSusChem · 2022Article
Corrections and comments
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Authors and funding
6 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Catalytic dehydrogenation enables reversible hydrogen storage in liquid organics as a critical technology to achieve carbon neutrality. However, oxidant or base-free catalytic dehydrogenation at mild temperatures remains a challenge. Here, we demonstrate a metal-free carbocatalyst, nitrogen-assembly carbons (NCs), for acceptorless dehydrogenation of N-heterocycles even at ambient temperature, showing greater activity than transition metal-based catalysts. Mechanistic studies indicate that the observed catalytic activity of NCs is because of the unique closely placed graphitic nitrogens (CGNs), formed by the assembly of precursors during the carbonization process. The CGN site catalyzes the activation of C─H bonds in N-heterocycles to form labile C─H bonds on catalyst surface. The subsequent facile recombination of this surface hydrogen to desorb H
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Registered trials
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