ArticleAngewandte Chemie (International ed. in English)2022
Identification of a Two-Coordinate Iron(I)-Oxalate Complex.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Triple-reaction-center catalysis drives simultaneous oxidation-reduction towards diverse emerging contaminants under oxidant-free conditions.Nature communications · 2026Article
- Identification of a Two-Coordinate Iron(I)-Oxalate Complex.Angewandte Chemie (International ed. in English) · 2022Article
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Authors and funding
6 authors.
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Abstract
Exotic oxidation states of the first-row transition metals have recently attracted much interest. In order to investigate the oxidation states of a series of iron-oxalate complexes, an aqueous solution of iron(III) nitrate and oxalic acid was studied by infrared free liquid matrix-assisted laser desorption/ionization as well as ionspray mass spectrometry. Here, we show that iron is not only detected in its common oxidation states +II and +III, but also in its unusual oxidation state +I, detectable in both positive-ion and in negative-ion modes, respectively. Vibrational spectra of the gas phase anionic iron oxalate complexes [Fe
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