ArticleAngewandte Chemie (International ed. in English)2022
Inverse Vulcanization of Norbornenylsilanes: Soluble Polymers with Controllable Molecular Properties via Siloxane Bonds.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
9 citing papers in PubMed, 38 citations in OpenAlex.
- Ageing of inverse vulcanised polymers.RSC applied polymers · 2026Article
- Metathesis-Sourced Epoxides in Ring-Opening Copolymerization: Selective Access to Degradable Polythioesters.Macromolecular rapid communications · 2026Article
- Monomer-Dependent Selectivity in Sulfur-Containing Ring-Opening Copolymerisation: Bimetallic Catalysis for Predictive Design of Degradable Polymers.Angewandte Chemie (International ed. in English) · 2025Article
- Kinetically Enhanced Access to a Dynamic Polyester Platform via Sequence Selective Terpolymerisation of Elemental Sulphur.Angewandte Chemie (International ed. in English) · 2025Article
- Sequence Control in Sulphur-Containing Ring-Opening Co- and Terpolymerisations.Angewandte Chemie (International ed. in English) · 2025Review
- Article
- Converting inorganic sulfur into degradable thermoplastics and adhesives by copolymerization with cyclic disulfides.Nature communications · 2024Article
- Poly(dithiophosphate)s, a New Class of Phosphorus- and Sulfur-Containing Functional Polymers by a Catalyst-Free Facile Reaction between Diols and Phosphorus Pentasulfide.International journal of molecular sciences · 2022Article
- Inverse Vulcanization of Norbornenylsilanes: Soluble Polymers with Controllable Molecular Properties via Siloxane Bonds.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
13 authors at 2 institutions in 2 countries.
Funding
Abstract
The inverse vulcanization produces high sulfur content polymers from alkenes and elemental sulfur. Control over properties such as the molar mass or the solubility of polymers is not well established, and existing strategies lack predictability or require large variations of the composition. Systematic design principles are sought to allow for a targeted design of materials. Herein, we report on the inverse vulcanization of norbornenylsilanes (NBS), with a different number of hydrolysable groups at the silicon atom. Inverse vulcanization of mixtures of NBS followed by polycondensation yielded soluble high sulfur content copolymers (50 wt % S) with controllable weight average molar mass (M
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.