Evidence map›Paper›PMID 35060687›Full record

ArticleChemistryOpen2022

(Dimesityl)boron Benzodithiophenes: Synthesis, Electrochemical, Photophysical and Theoretical Characterization.

Luigi Menduti, Clara Baldoli, Serena Arnaboldi, Andreas Dreuw, Duygu Tahaoglu, Alberto Bossi, Emanuela Licandro

Abstract read
In one paragraph

Article in ChemistryOpen, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. (BO)Angewandte Chemie (International ed. in English) · 2023
    Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Luigi MendutiDepartment of Chemistry, University of Milan, Via C. Golgi 19, 20133, Milano, Italy.ORCID http://orcid.org/0000-0002-7613-1563
Clara BaldoliCNR-Institute of Chemical Sciences and Technologies (SCITEC) "Giulio Natta" and SmartMatLab Centre, Via C. Golgi 19, 20133, Milano, Italy.ORCID http://orcid.org/0000-0001-5504-8624
Serena ArnaboldiDepartment of Chemistry, University of Milan, Via C. Golgi 19, 20133, Milano, Italy.ORCID http://orcid.org/0000-0002-1981-4659
Andreas DreuwInterdisciplinary Center for Scientific Computing, University of Heidelberg, Im Neuenheimer Feld 205, 69120, Heidelberg, Germany.ORCID http://orcid.org/0000-0002-5862-5113
Duygu TahaogluInterdisciplinary Center for Scientific Computing, University of Heidelberg, Im Neuenheimer Feld 205, 69120, Heidelberg, Germany.
Alberto BossiCNR-Institute of Chemical Sciences and Technologies (SCITEC) "Giulio Natta" and SmartMatLab Centre, Via C. Golgi 19, 20133, Milano, Italy.ORCID http://orcid.org/0000-0001-9252-6218
Emanuela LicandroDepartment of Chemistry, University of Milan, Via C. Golgi 19, 20133, Milano, Italy.ORCID http://orcid.org/0000-0003-0168-9295

Funding

Progetto Accordo Quadro Regione Lombardia - CNR 2016 "I-ZEBProgetto integrato Regione Lombardia - Fondazione Cariplo 2014 "SmartMatLab Centre"University of Milan through the APC initiative
6 · The paper itself

Abstract

Triarylboranes containing linear or angular benzodithiophene moieties and bearing one or two dimesitylboron units were synthesized. The electrochemical and optical features of these compounds were investigated by cyclic voltammetry, UV/Vis and fluorescence spectroscopy while DFT calculations were run to analyze the energetic landscape of these systems. For both linear and angular benzodithiophenes, symmetrical disubstitution leads to the highest photoluminescence yields. The linear benzodithiophene disubstituted with two dimesitylboron units proved to be the most interesting and promising molecule as an electron-transport material for organic electronics owing to its LUMO energy level of -2.84 eV which is close to those of commonly used electron transport materials like bathocuproine or bathophenantroline.

Indexed as

benzodithiophenesboronfunctional materialssulfur heterocyclestriarylboranes

Identifiers

PMID35060687
PMCPMC8780079

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.