Evidence map›Paper›PMID 35050605›Full record

ArticleJournal of the American Chemical Society2022

Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes.

Blaise L Geoghegan, Yang Liu, Sergey Peredkov, Sebastian Dechert, Franc Meyer, Serena DeBeer, George E Cutsail

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 33 papers.

0numbers the graph read from it
0cells of the map it votes in
33citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

33 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Journal of the American Chemical Society · 2025
    Article
  9. Article
  10. Article
  11. Article
  12. Platform Design Enabling Silver(III) Stabilization ─ The Uprise of AgChemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Review
  13. Cation-Site Disordered CuSmall (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  14. In situ stabilization of CuNature communications · 2025
    Article
  15. Article
  16. Article
  17. Copper-Mediated -CF(OCFACS organic & inorganic Au · 2024
    Article
  18. Article
  19. Review
  20. X-ray absorption and emission spectroscopy of NDalton transactions (Cambridge, England : 2003) · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Blaise L GeogheganMax Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470 Mülheim an der Ruhr, Germany.ORCID 0000-0001-9543-102X
Yang LiuInstitute of Inorganic Chemistry, University of Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany.ORCID 0000-0002-2486-8520
Sergey PeredkovMax Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470 Mülheim an der Ruhr, Germany.
Sebastian DechertInstitute of Inorganic Chemistry, University of Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany.ORCID 0000-0002-2864-2449
Franc MeyerInstitute of Inorganic Chemistry, University of Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany.ORCID 0000-0002-8613-7862
Serena DeBeerMax Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470 Mülheim an der Ruhr, Germany.ORCID 0000-0002-5196-3400
George E CutsailMax Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470 Mülheim an der Ruhr, Germany.ORCID 0000-0002-7378-9474

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A series of organometallic copper complexes in formal oxidation states ranging from +1 to +3 have been characterized by a combination of Cu K-edge X-ray absorption (XAS) and Cu Kβ valence-to-core X-ray emission spectroscopies (VtC XES). Each formal oxidation state exhibits distinctly different XAS and VtC XES transition energies due to the differences in the Cu Z

Identifiers

PMID35050605
PMCPMC8855422

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.