ArticleNature communications2022
Mechanically robust supramolecular polymer co-assemblies.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
14 citing papers in PubMed.
- Impact of Threading State on the Mechanics of γ-Cyclodextrin-Pyrene Gels.Angewandte Chemie (International ed. in English) · 2026Article
- Macroscopically anisotropic supramolecular materials prepared from an undercooled liquid-crystalline phase of a cholesterol-based low-molecular-weight compound.Nature communications · 2026Article
- From β-Dicarbonyl Chemistry to Dynamic Polymers.Chemical reviews · 2025Review
- Healable Glassy Metallosupramolecular Polymers.ACS macro letters · 2025Article
- High Molecular Weight Protein-Like Semiflexible Chains via Bioorthogonal Polymerization of Coiled-Coil Peptides.Macromolecules · 2024Article
- Bridge-rich and loop-less hydrogel networks through suppressed micellization of multiblock polyelectrolytes.Nature communications · 2024Article
- Semi-crystalline polymers with supramolecular synergistic interactions: from mechanical toughening to dynamic smart materials.Chemical science · 2024Review
- Bulk transparent supramolecular glass enabled by host-guest molecular recognition.Nature communications · 2024Article
- Highly robust supramolecular polymer networks crosslinked by a tiny amount of metallacycles.Nature communications · 2024Article
- Hyperbranched Dynamic Crosslinking Networks Enable Degradable, Reconfigurable, and Multifunctional Epoxy Vitrimer.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Unexpected structural complexity of d-block metallosupramolecular architectures within the benzimidazole-phenoxo ligand scaffold for crystal engineering aspects.Scientific reports · 2023Article
- Designing supramolecular self-assembly nanomaterials as stimuli-responsive drug delivery platforms for cancer therapy.iScience · 2023Review
- Plasticization of a Semicrystalline Metallosupramolecular Polymer Network.ACS polymers Au · 2023Article
- Metallosupramolecular polymers as precursors for platinum nanocomposites.Polymer chemistry · 2022Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Supramolecular polymers are formed through non-covalent, directional interactions between monomeric building blocks. The assembly of these materials is reversible, which enables functions such as healing, repair, or recycling. However, supramolecular polymers generally fail to match the mechanical properties of conventional commodity plastics. Here we demonstrate how strong, stiff, tough, and healable materials can be accessed through the combination of two metallosupramolecular polymers with complementary mechanical properties that feature the same metal-ligand complex as binding motif. Co-assembly yields materials with micro-phase separated hard and soft domains and the mechanical properties can be tailored by simply varying the ratio of the two constituents. On account of toughening and physical cross-linking effects, this approach affords materials that display higher strength, toughness, or failure strain than either metallosupramolecular polymer alone. The possibility to combine supramolecular building blocks in any ratio further permits access to compositionally graded objects with a spatially modulated mechanical behavior.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.