Evidence map›Paper›PMID 35038188›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Remote Oxidative Activation of a [Cp*Rh] Monohydride.

Emily A Boyd, Julie A Hopkins Leseberg, Emma L Cosner, Davide Lionetti, Wade C Henke, Victor W Day, James D Blakemore

Open access · greenAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
0.2field-weighted citation impact, top 64% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 2 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 2 institutions in 1 country.

Emily A BoydDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, Kansas, 66045, United States.
Julie A Hopkins LesebergDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, Kansas, 66045, United States.
Emma L CosnerDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, Kansas, 66045, United States.
Davide LionettiDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, Kansas, 66045, United States.
Wade C HenkeDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, Kansas, 66045, United States.
Victor W DayDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, Kansas, 66045, United States.
James D BlakemoreDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, Kansas, 66045, United States.ORCID http://orcid.org/0000-0003-4172-7460
University of Kansas · USCalifornia Institute of Technology · US

Funding

Avance II 500 High Performance Digital NMR Spectrometer SystemS10RR024664 · NCRR · UNIVERSITY OF KANSAS LAWRENCE · PI VANDERVELDE, DAVID G · 2007 to 2007
$468k
AVIII HD 400 NMR spectrometer to replace existing DRX 400S10OD016360 · OD · UNIVERSITY OF KANSAS LAWRENCE · PI DOUGLAS, JUSTIN TRIGALET · 2014 to 2014
$297k
National Science Foundation CHE-1625923National Science Foundation OIA-1833087NCRR NIH HHS S10 RR024664NIH HHS S10 OD016360NIH HHS S10OD016360NIH HHS S10RR024664
6 · The paper itself

Abstract

Half-sandwich rhodium monohydrides are often proposed as intermediates in catalysis, but little is known regarding the redox-induced reactivity accessible to these species. Herein, the bis(diphenylphosphino)ferrocene (dppf) ligand has been used to explore the reactivity that can be induced when a [Cp*Rh] monohydride undergoes remote (dppf-centered) oxidation by 1e

Indexed as

crystallographyelectrochemistryhydridesligandsredox chemistry

Identifiers

PMID35038188
PMCPMC8891045
OpenAlexW4206486933

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.