Evidence map›Paper›PMID 35031615›Full record

ArticleNature communications2022

Uncovering the reaction mechanism behind CoO as active phase for CO

Iris C Ten Have, Josepha J G Kromwijk, Matteo Monai, Davide Ferri, Ellen B Sterk, Florian Meirer, Bert M Weckhuysen

Abstract read
In one paragraph

Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.

0numbers the graph read from it
0cells of the map it votes in
28citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

28 citing papers in PubMed.

  1. Microwave-driven CORSC advances · 2026
    Article
  2. Harnessing Selectivity in COACS environmental Au · 2026
    Review
  3. Article
  4. The Chemistry of COChemical reviews · 2026
    Review
  5. Article
  6. Advancing Sustainability in Hydrocarbon Production: Breakthroughs in COIndustrial & engineering chemistry research · 2026
    Article
  7. Article
  8. The Electronic Structure of Planar Rhombic CoThe journal of physical chemistry. A · 2026
    Article
  9. Efficient CONature nanotechnology · 2026
    Article
  10. Review
  11. Article
  12. Flame Synthesized Co-CeOACS catalysis · 2025
    Article
  13. Article
  14. Article
  15. Article
  16. RuCo/ZrOAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024
    Article
  17. COAccounts of chemical research · 2024
    Article
  18. Article
  19. Article
  20. Multivariate Bayesian Optimization of CoO Nanoparticles for COJournal of the American Chemical Society · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Iris C Ten HaveInorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands.ORCID http://orcid.org/0000-0001-7863-6197
Josepha J G KromwijkInorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands.
Matteo MonaiInorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands.ORCID http://orcid.org/0000-0001-6945-4391
Davide FerriPaul Scherrer Institute, Forschungsstrasse 111, 5232, Villigen, Switzerland.ORCID http://orcid.org/0000-0002-9354-5231
Ellen B SterkInorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands.
Florian MeirerInorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands. f.meirer@uu.nl.ORCID http://orcid.org/0000-0001-5581-5790
Bert M WeckhuysenInorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands. b.m.weckhuysen@uu.nl.ORCID http://orcid.org/0000-0001-5245-1426

Funding

Nederlandse Organisatie voor Wetenschappelijk Onderzoek (Netherlands Organisation for Scientific Research) Gravitation Program MCEC
6 · The paper itself

Abstract

Transforming carbon dioxide into valuable chemicals and fuels, is a promising tool for environmental and industrial purposes. Here, we present catalysts comprising of cobalt (oxide) nanoparticles stabilized on various support oxides for hydrocarbon production from carbon dioxide. We demonstrate that the activity and selectivity can be tuned by selection of the support oxide and cobalt oxidation state. Modulated excitation (ME) diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) reveals that cobalt oxide catalysts follows the hydrogen-assisted pathway, whereas metallic cobalt catalysts mainly follows the direct dissociation pathway. Contrary to the commonly considered metallic active phase of cobalt-based catalysts, cobalt oxide on titania support is the most active catalyst in this study and produces 11% C

Identifiers

PMID35031615
PMCPMC8760247

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.