ArticleJournal of the American Chemical Society2022
Sugar-Based Polymers with Stereochemistry-Dependent Degradability and Mechanical Properties.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 10 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
10 citing papers in PubMed.
- Shaping a Circular Future with Bio-derived Resins in Additive Manufacturing.Accounts of materials research · 2026Article
- Supra-biomimetic Impact-Resistant Composites via Harnessing Macro-Microscale Competition.Research (Washington, D.C.) · 2026Article
- Effects of Isohexide Stereochemistry on Vinylogous Urethane Covalent Adaptable Networks.Macromolecules · 2025Article
- A recyclable polyester library from reversible alternating copolymerization of aldehyde and cyclic anhydride.Nature communications · 2023Article
- Precision native polysaccharides from living polymerization of anhydrosugars.Nature chemistry · 2023Article
- Structural Metamorphoses of d-Xylose Oxetane- and Carbonyl Sulfide-Based PolymersJournal of the American Chemical Society · 2023Article
- Design of Microstructure-Engineered Polymers for Energy and Environmental Conservation.JACS Au · 2023Review
- Poly(glycidyl azide) as Photo-Crosslinker for Polymers.Polymers · 2022Article
- Click Step-Growth Polymerization andAccounts of chemical research · 2022Article
- Ultra-Tough Elastomers from Stereochemistry-Directed Hydrogen Bonding in Isosorbide-Based Polymers.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
- Erratum issued
Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Stereochemistry in polymers can be used as an effective tool to control the mechanical and physical properties of the resulting materials. Typically, though, in synthetic polymers, differences among polymer stereoisomers leads to incremental property variation, i.e., no changes to the baseline plastic or elastic behavior. Here we show that stereochemical differences in sugar-based monomers yield a family of nonsegmented, alternating polyurethanes that can be either strong amorphous thermoplastic elastomers with properties that exceed most cross-linked rubbers or robust, semicrystalline thermoplastics with properties comparable to commercial plastics. The stereochemical differences in the monomers direct distinct intra- and interchain supramolecular hydrogen-bonding interactions in the bulk materials to define their behavior. The chemical similarity among these isohexide-based polymers enables both statistical copolymerization and blending, which each afford independent control over degradability and mechanical properties. The modular molecular design of the polymers provides an opportunity to create a family of materials with divergent properties that possess inherently built degradability and outstanding mechanical performance.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.