ArticleChemical science2021
Porphyrin-based donor-acceptor COFs as efficient and reusable photocatalysts for PET-RAFT polymerization under broad spectrum excitation.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed.
- Multidimensional Unraveling Insights from an Enzyme-Nanozyme Cascade-Based Electrochemical Biosensor for Screening Microplastic Neurotoxicity.Environment & health (Washington, D.C.) · 2026Article
- COFs in Action: Advanced Approaches for Monitoring Uranium, Mercury, Lead, and Nitro Compounds in Environmental Contaminants.Topics in current chemistry (Cham) · 2026Review
- Porous Organic Polymers with Azo, Azoxy, and Azodioxy Linkages: Design, Synthesis, and COPolymers · 2026Review
- Article
- Trans-AAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Self-assembled [2 + 3] organic-imine cage as an artificial light harvester for the photocatalytic organic transformation in an aqueous medium.RSC advances · 2025Article
- Highly Entangled, Mechanically Robust Hydrogel Thin Films for Passive Cooling Materials via Open-Vessel Fabrication.Gels (Basel, Switzerland) · 2025Article
- Photo-RAFT Polymerization Under Microwatt Irradiation via Unimolecular Photoinduced Electron Transfer.Angewandte Chemie (International ed. in English) · 2025Article
- Synergistic experimental and computational investigation of azo-linked porphyrin-based porous organic polymers for CORSC advances · 2025Article
- Modular reductive radical-polar crossover-based acyl migration reactions ofRSC advances · 2025Article
- Syndiospecific polymerization of styrene with half-titanocene catalysts containing fluorinated phenoxy ligands.RSC advances · 2025Article
- Controllable synthesis of Co/NC catalysts with high-density Co-NRSC advances · 2024Article
- A General Synthesis Method for Covalent Organic Framework and Inorganic 2D Materials Hybrids.Precision chemistry · 2024Article
- 3-(Sulfamic acid)-propyltriethoxysilane on biochar nanoparticles as a practical, biocompatible, recyclable and chemoselective nanocatalyst in organic reactions.RSC advances · 2024Article
- Highly dispersed noble metal nanoparticle composites on biomass-derived carbon-based carriers: synthesis, characterization, and catalytic applications.RSC advances · 2024Article
- Identification of two-dimensional covalent organic frameworks withChemical science · 2024Article
- Microwave absorbing characteristics of porphyrin derivates: a loop of conjugated structure.RSC advances · 2023Article
- Three-dimensional covalent organic frameworks with pto and mhq-z topologies based on Tri- and tetratopic linkers.Nature communications · 2023Article
- Electrocatalytic Porphyrin/Phthalocyanine-Based Organic Frameworks: Building Blocks, Coordination Microenvironments, Structure-Performance Relationships.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Review
- Tuning excited state electronic structure and charge transport in covalent organic frameworks for enhanced photocatalytic performance.Nature communications · 2023Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Covalent organic frameworks (COFs) are crystalline and porous organic materials attractive for photocatalysis applications due to their structural versatility and tunable optical and electronic properties. The use of photocatalysts (PCs) for polymerizations enables the preparation of well-defined polymeric materials under mild reaction conditions. Herein, we report two porphyrin-based donor-acceptor COFs that are effective heterogeneous PCs for photoinduced electron transfer-reversible addition-fragmentation chain transfer (PET-RAFT). Using density functional theory (DFT) calculations, we designed porphyrin COFs with strong donor-acceptor characteristics and delocalized conduction bands. The COFs were effective PCs for PET-RAFT, successfully polymerizing a variety of monomers in both organic and aqueous media using visible light (
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