ReviewChemical science2021
Uncommon carbene insertion reactions.
Review in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
17 citing papers in PubMed, 107 citations in OpenAlex.
- Aromatization-Driven Borylene Generation from Borepin Precursors Enables Fused Borirane Synthesis and Selective Alkene Functionalization.Journal of the American Chemical Society · 2026Article
- Palladium-catalyzed borylative coupling of hypervalent iodine diazo reagents with boranes for the synthesis of organoboron carboxylate.Molecular diversity · 2026Article
- Carbene-Ketene Formal [3 + 2] Cycloaddition Enabled by Visible-Light-Induced Dual Photolysis of Diazo Compounds.JACS Au · 2026Article
- Properties of Bisdiazo Compounds and Their Derived Carbenes via Density Functional Theory.Chemphyschem : a European journal of chemical physics and physical chemistry · 2026Article
- Tunable Skeletal Editing of Benzothiazole and Benzisothiazole Via Carbene Transfer Reactions.JACS Au · 2025Article
- Iron-Catalyzed Intermolecular N-H Insertion Using Acceptor-Acceptor Carbenes Derived from Iodonium Ylides.Organic letters · 2025Article
- Metal-Catalyzed Fluoroacetyl Carbene Transfer from Sulfonium Salts.Organic letters · 2025Article
- Catalytic insertion of nitrenes into B-H bonds.Chemical science · 2025Article
- Rhodium-catalyzed transformations of diazo compoundsRSC advances · 2024Review
- Photoinduced Copper-Catalyzed Cross-Coupling of Acylsilanes with Heteroarenes via Bimetallic Relay.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Direct synthesis of α-functionalized amides via heteroatom-hydrogen insertion reactions using amide-sulfoxonium ylides.Nature communications · 2024Article
- Visible-light-mediated deoxygenative transformation of 1,2-dicarbonyl compounds through energy transfer process.Nature communications · 2024Article
- Enantioselective copper-catalyzed B-H bond insertion reaction of α-diazo phosphonates to access chiral α-boryl phosphonates.Chemical science · 2024Article
- Wittig/B─H insertion reaction: A unique access to trisubstitutedScience advances · 2023Article
- ChiralChemical science · 2023Article
- Covalent Functionalization of Black Phosphorus Nanosheets with Dichlorocarbenes for Enhanced Electrocatalytic Hydrogen Evolution Reaction.Nanomaterials (Basel, Switzerland) · 2023Article
- Fe-Catalyzed Selective Formal Insertion of Diazo Compounds into C(sp)-C(spACS central science · 2022Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Transition-metal-catalysed carbene insertion reaction is a straightforward and efficient protocol for the construction of carbon-carbon or carbon-heteroatom bonds. Compared to the intensively studied and well-established "common" carbene insertion reactions, including carbene insertion into C-H, Si-H, N-H, O-H, and S-H bonds, several "uncommon" carbene insertion reactions, including carbene insertion into B-H, Sn-H, Ge-H, P-H, F-H, C-C, and M-M bonds, have been neglected for a long time. However, more and more studies on uncommon carbene insertion reactions have been disclosed recently, and clearly demonstrate the great synthetic potential of these reactions. The current perspective reviews the history and the newest advances of uncommon carbene insertion reactions, discusses their potential applications and challenges, and also presents an outlook of this promising field.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.