ArticleAngewandte Chemie (International ed. in English)2022
Calix[4]pyrrolato Stannate(II): A Tetraamido Tin(II) Dianion and Strong Metal-Centered σ-Donor.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- An Iridium Distannylidyne - Expanding the Scope of Tetrylidyne Transition Metal Coordination Chemistry.Angewandte Chemie (International ed. in English) · 2026Article
- Isolation and Reactivity of a Square-Planar Trisamido Silane.Angewandte Chemie (International ed. in English) · 2026Article
- En Route to a Molecular Terminal Tin Oxide.Inorganic chemistry · 2024Article
- A crystalline T-shaped planar group 14 anion.Chemical science · 2023Article
- Metallomimetic Chemistry of a Cationic, Geometrically Constrained Phosphine in the Catalytic Hydrodefluorination and Amination of Ar-F Bonds.Journal of the American Chemical Society · 2023Article
- Dual Reactivity of a Geometrically Constrained Phosphenium Cation.Angewandte Chemie (International ed. in English) · 2022Article
- Geometrically constrained square pyramidal phosphoranide.Chemical science · 2022Article
- Calix[4]pyrrolato Stannate(II): A Tetraamido Tin(II) Dianion and Strong Metal-Centered σ-Donor.Angewandte Chemie (International ed. in English) · 2022Article
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2 authors.
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Abstract
Anionic, metal-centered nucleophiles are emerging compounds with unique reactivities. Here, we describe the isolation and full characterization of the first tetraamido tin(II) dianion, its behavior as ligand towards transition metals, and its reactivity as a tin-centered nucleophile. Experimental values such as the Tolman electronic parameter (TEP) and computations attest tin-located σ-donor ability exceeding that of carbenes or electron-rich phosphines. Against transition metals, the stannate(II) can act as η
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